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用化学方法在聚丙烯微孔膜表面上接枝丙烯酰胺.利用红外光谱,X射线光电子能谱,扫描电镜,原子力显微镜观察了膜表面形态和微观结构的变化,同时考察了膜的接触角和吸水能力,对BSA蛋白质的吸附量及水通量和抗污染能力.结果表明,随着接枝率的提高,接触角从95°减小到38°,吸水率也提高到163.9%.改性后,PP膜对BSA的吸附减少,膜的水通量减小,但同时膜的污染率下降,当接枝率为11.5%时,膜的污染率为0.274,比接枝前下降了55%.改性后PP微孔膜的亲水性和抗污染能力得到较大提高.

参考文献

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[2] Wavhal DS.;Fisher ER. .Membrane surface modification by plasma-induced polymerization of acrylamide for improved surface properties and reduced protein fouling[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(1):79-85.
[3] 王香梅,张菁,王庆瑞.等离子体引发接枝聚合改善聚丙烯表面的亲水性[J].高分子材料科学与工程,2005(05):78-81.
[4] Yu HY;Xu ZK;Yang Q;Hu MX;Wang SY .Improvement of the antifouling characteristics for polypropylene microporous membranes by the sequential photoinduced graft polymerization of acrylic acid[J].Journal of Membrane Science,2006(1/2):658-665.
[5] Jin Kie Shim;Hee Seok Na;Hoon Huh;Young Moo Lee;Young Chang Nho .Surface modification of polypropylene membranes by #gamma#-ray induced graft copolymerization and their solute permeation characteristics[J].Journal of Membrane Science,2001(2):215-226.
[6] Wang Y.;Choo KH.;Lee YS.;Lee CH.;Kim JH. .Hydrophilic modification of polypropylene microfiltration membranes by ozone-induced graft polymerization[J].Journal of Membrane Science,2000(2):269-276.
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[8] Kou RQ.;Xu ZK.;Deng HT.;Liu ZM.;Seta P.;Xu YY. .Surface modification of microporous polypropylene membranes by plasma-induced graft polymerization of alpha-allyl glucoside[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(17):6869-6875.
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