B4C与Ti在1800°C×35MPa×1h的烧结条件下反应生成了TiB2 棒晶,棒晶长度在10~30μm,其长径比在2~8范围.原位生成的棒晶赋予了材料具有极高的力学性能,材料的弯曲强度和断裂韧性分别为 680MPa和 12MPa·m1/2.通过 X射线衍射检测了材料的物相组成,利用扫描电镜及透射电镜观察了材料的显微结构.最后讨论了温度及金属Ti含量对棒晶TiB2的生成及发育的影响.
The rod-like phases TiB2 were formed by the reaction of B4C and Ti under 1800℃×35MPa×1h
sintering condition, the length of particle TiB2 was 10~30μm, some over 40μm; and the aspect ratio was 2~8. These rod-like phases
endowed the composites with high mechanical properties. The bending strength and the fracture toughness of the composites were 680MPa and 12MPa·m1/2,
respectively. The phases were examined by XRD; the microstructure of the composites was observed by SEM and TEM. The influence of sintering
temperature and Ti content on the growth and development of rod-like phases TiB2 was discussed.
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