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采用接枝的方法在丁腈-40分子链中接入羧基,获得了高门尼黏度的羧基丁腈橡胶,并用其对环氧树脂进行改性,从而制备出耐高温环氧树脂结构胶.通过加入促进剂可将固化温度从180℃降至120℃.

参考文献

[1] 胡海华,李锦山,朱景芬.羧基丁腈橡胶的硫化性能[J].合成橡胶工业,2005(05):336-339.
[2] Dispenza C;Spadaro G;McGrail PT .The influence of the rubber carboxyl functionality on the processability and properties of solid rubber modified epoxy mixtures[J].Macromolecular chemistry and physics,2005(3):393-403.
[3] Thomas R;Abraham J;Thomas S;Thomas S .Influence of carboxyl-terminated (butadiene-co-acrylonitrile) loading on the mechanical and thermal properties of cured epoxy blends[J].Journal of Polymer Science, Part B. Polymer Physics,2004(13):2531-2544.
[4] Huang F.;Liu YQ.;Zhang XH.;Wei GS.;Gao JM.;Song ZH.;Zhang ML.;Qiao JL. .Effect of elastomeric nanoparticles on toughness and heat resistance of epoxy resins[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2002(13):786-790.
[5] 黄文霖,单国荣,翁志学.双酚A及端羧基丁腈橡胶对环氧树脂的增韧作用[J].合成橡胶工业,2007(02):119-123.
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