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研究了Cu、Ni在含铜时效钢表面氧化层中的富集规律。研究发现,无Ni含铜钢在1100~1200 ℃会形成液态富铜相,并向奥氏体晶界渗透,成为表面裂纹源。而在1000 ℃和1300 ℃均不形成液态富铜相。Ni加入到含铜钢中,改变了氧化层中富铜相的结构,促进了NiCu富集相以颗粒状保留在氧化层内,抑制了Cu向基体中的渗透,从而改善了含铜时效钢的热脆性问题。

Enrichment of Cu,Ni in surface oxidation layer of copperbearing agehardening steel was investigated. The results showed that copper enriched liquid phase is formed at reheating temperature of 1100~1200 ℃, and the liquid Cu enriched phase is penetrated along austenite grain boundary leading to surface cracking. But copper enriched liquid phase is not formed at reheating temperature of 1000 ℃ and 1300 ℃. The structure of copperrich phase in scale is changed by addition of nickel, and NiCu enriched phase is stayed in oxidized layer in form of granular particle which inhibits copper enriched phase from penetration into the base metal.

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