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  4. 可见光响应C掺杂纳米TiO2的研究进展

材料导报, 2010, 24(21): 129-133.

可见光响应C掺杂纳米TiO2的研究进展

聂龙辉 1, , 徐洪涛 2,

1.湖北工业大学化学与环境工程学院,武汉,430068

2.湖北工业大学化学与环境工程学院,武汉,430068

基金项目:   湖北工业大学博士启动基金  

关键词： c掺杂 , TiO2 , 可见光活性

Research Progress in Visible-light Response of C-doped Nano TiO2

纳米TiO_2的禁带宽度(3.2 Ev)限制了对太阳光能的利用,对纳米TiO2进行掺C改性能减小带隙、显著提高对可见光的利用,同时保持紫外光光催化活性,显示出良好的应用前景.综述和分析了C掺杂纳米TiO2的可见光活性理论、制备方法、在环境污染治理等方面的应用,及C和其它元素共掺杂改性TiO2的研究.总结了C掺杂纳米TiO2研究中存在的问题,并讨论了今后的研究方向.

参考文献

[1] Wang R;Hashimoto K;Fujishima A et al.Light-induced amphiphilic surfaces[J].Nature,1997,338(37):431.
[2] 籍宏伟,马万红,黄应平,赵进才,王正平.可见光诱导TiO2光催化的研究进展[J].科学通报,2003(21):2199-2204.
[3] 侯廷红,毛健,涂铭旌,王彬,杨玲,张小丽.纳米TiO2光催化剂可见光活性研究进展[J].功能材料,2004(z1):1946-1950.
[4] 彭涛,周曦,李远志.可见光响应纳米TiO2光催化材料研究进展[J].中国科技论文在线,2009(04):302-307.
[5] Asahi R;Morikawa T;Ohwaki T et al.Visible light photocatalysis in nitrogen-doped titanium oxides[J].Science,2001,293(5528):269.
[6] 顾德恩,杨邦朝,胡永达.非金属元素掺杂TiO2的可见光催化活性研究进展[J].功能材料,2008(01):1-5.
[7] Khan S U M;Al-Shahry M;Ingler Jr W B .Efficient photochemical water splitting by a chemically modified n-TiO2[J].Science,2002,297:2243.
[8] Lee JY;Park J;Cho JH .Electronic properties of N- and C-doped TiO2[J].Applied physics letters,2005(1):1904-1-1904-3-0.
[9] Nakano, Y;Morikawa, T;Ohwaki, T;Taga, Y .Electrical characterization of band gap states in C-doped TiO2 films[J].Applied Physics Letters,2005(5):2111-1-2111-3-0.
[10] Chen X;Glans PA;Qiu X;Dayal S;Jennings WD;Smith KE;Burda C;Guo J .X-ray spectroscopic study of the electronic structure of visible-light responsive N-, C- and S-doped TiO2[J].Journal of Electron Spectroscopy and Related Phenomena,2008(2):67-73.
[11] Valentin C D;Paccioni G;Selloni A .Theory of carbon doping of titanium dioxide[J].Chemistry of Materials,2005,17:6656.
[12] 田凤惠 .非金属元素掺杂改性的TiO<,2>基光催化剂的理论研究[D].山东大学,2006.
[13] Enrique A. Reyes-Garcia;Yanping Sun;Karla R. Reyes-Gil;Daniel Raftery .Solid-state NMR and EPR analysis of carbon-doped titanium dioxide photocatalysts (TiO{sub}(2-x)C{sub}x)[J].Solid State Nuclear Magnetic Resonance,2009(2):74-81.
[14] Li YZ;Hwang DS;Lee NH;Kim SJ .Synthesis and characterization of carbon-doped titania as an artificial solar light sensitive photocatalyst[J].Chemical Physics Letters,2005(1/3):25-29.
[15] 刘长虹.非金属元素掺杂TiO2可见光催化剂[J].唐山师范学院学报,2007(02):17-19.
[16] 田地,余刚,张彭义,陈中颖.碳黑改性二氧化钛对气相中甲苯的光催化降解[J].太阳能学报,2002(01):66-69.
[17] Hamal D B;Klabunde D J et al.Synthesis,characterization,and visible light activity of new nanoparticle photocatalysts based on silver,carbon,and sulfur-doped TiO2[J].Journal of Colloid and Interface Science,2007,311:514.
[18] Qi Xiao;Jiang Zhang;Chong Xiao;Zhichun Si;Xiaoke Tan .Solar photocatalytic degradation of methylene blue in carbon-doped TiO_2 nanoparticles suspension[J].Solar Energy,2008(8):706-713.
[19] Xiao Q;Ouyang L L .Pbotocatalytic activity and hydroxyl radical formation of carbon-doped TiOz nanocrystalline:Effect of calcinations temperature[J].Chemical Engineering Journal,2009,148:248.
[20] Treschev SY;Chou PW;Tseng YH;Wang JB;Perevedentseva EV;Cheng CL .Photoactivities of the visible-light-activated mixed-phase carbon-containing titanium dioxide: The effect of carbon incorporation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2008(1):8-16.
[21] Xu J W;Wang Y F;Li Z H et al.Preparation and electrochemical properties of carbon-doped TiOz nanotube as an anode material for lithium-ion batteries[J].Journal of Power Sources,2008,178:903.
[22] Wang X X;Song X M;Lin M et al.Surface initiated graft polymerization from carbon-doped TiOz nanoparticles under sunlight illumination[J].Polymer,2007,48:5834.
[23] Choi Y;Umebayashi T;Yoshikaw M .Fabrication and characterization of C-doped anatase TiOz photocatalysts[J].Journal of Materials Science,2004,39(05):1837.
[24] Wu Z B;Dong F;Liu Y et al.Enhancement of the visible light photocatalytic performance of C-doped TiOz by loading with V2 O_5[J].Catalysis Communications,2009,11:82.
[25] Hiroshi Irie;Yuka Watanabe;Kazuhito Hashimoto .Carbon-doped Anatase TiO_2 Powders as a Visible-light Sensitive Photocatalyst[J].Chemistry Letters,2003(8):772-773.
[26] Choi Y;Umebayashi T;Yamamoto S .Fabrication of TiO2 photocatalysts by oxidative annealing of TiC[J].Journal of Materials Science Letters,2003,22:1209.
[27] Janus M;Tryba B;Inagaki M.New preparation of a carbon TiO2 photocatalyst by carbonization of n-hexane deposited on TiO2[J].Applied Catalysis B:Environmental,2004(52):61.
[28] Sugiyama K.;Ogawa T.;Saito N.;Hosoya Y.;Yajima T. .Surface characterization of titanium dioxide powder treated by the CH4-H-2 plasma CVD method[J].Surface & Coatings Technology,2003(0):882-885.
[29] Park J W;Kim D W;Seon H S et al.Synthesis of carbondoped TiOz nanoparticle using COz decomposition by thermal plasma[J].Thin Solid Films,2010,518(15):4113.
[30] Ren WJ;Ai ZH;Jia FL;Zhang LZ;Fan XX;Zou ZG .Low temperature preparation and visible light photocatalytic activity of mesoporous carbon-doped crystalline TiO2[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(3/4):138-144.
[31] Wang S H;Chen T K;Rao K et al.Nanocolumnar titania thin films uniquely incorporated with carbon for visible light photocatalysis[J].Appl Cataly B:Environ,2007,76:328.
[32] Irie H;Washizuka S;Hashimoto K .Hydrophilicity on carbon-doped TiO2 thin films under visible light[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1/2):21-25.
[33] Jong Hyeok Park;Sungwook Kim;Allen J.Bard .Novel Carbon-Doped TiO_2 Nanotube Arrays with High Aspect Ratios for Efficient Solar Water Splitting[J].Nano letters,2006(1):24-28.
[34] Zhou B;Schulz M;Lin Y H et al.Photoelectrochemical generation of hydrogen carbon-doped TiO2 photoanode[J].Appl Cataly B:Environ,2009,92:41.
[35] Chen C;Long M;Zeng H et al.Prepartion,characterization and visible-light activity of carbon modified TiO2 with two kinds of carbonaceous species[J].Journal of Molecular Catalysis A:Chemical,2009,314:35.
[36] A novel Ce, C-codoped TiO_2 nanoparticles and its photocatalytic activity under visible light[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(3):884.
[37] Ohno, T;Tsubota, T;Toyofuku, M;Inaba, R .Photocatalytic activity of a TiO2 photocatalyst doped with C4+ and S4+ ions having a rutile phase under visible light[J].Catalysis Letters,2004(4):255-258.
[38] Xu C;Killmeyer R;Gray ML;Khan SUM .Photocatalytic effect of carbon-modified n-TiO2 nanoparticles under visible light illumination[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2006(3/4):312-317.
[39] Cong Y;Chen F;Zhang J et al.Carbon and nitrogen-co-doped TiO2 with visible light photocatalytic activity[J].Chemistry Letters,2006,35:800.
[40] 石健,李军,蔡云法.具有可见光响应的C、N共掺杂TiO2纳米管光催化剂的制备[J].物理化学学报,2008(07):1283-1286.
[41] Sano T.;Negishi N.;Koike K.;Takeuchi K.;Matsuzawa S. .Preparation of a visible light-responsive photocatalyst from a complex of Ti4+ with a nitrogen-containing ligand[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2004(3):380-384.
[42] 殷澍,Maskazu Komatsu,张其武,李锐星,唐清,Fumio Saito,Tsugio Sato.Mechanochemical Synthesis of Visible-light Induced Photocatalyst with Nitrogen and Carbon Doping[J].过程工程学报,2006(03):477-481.
[43] Gorska P;Zaleska A;Hupka J .Photodegradation of phenol by UV/TiO2 and Vis/N,C-TiO2 processes:Comparative mechanistic and kinetic studies[J].Sep Purif Techn,2009,68:90.
[44] Zhang S J;Song L M .Preparation of visible-light-active carbon and nitrogen codoped titanium dioxide photocatalysts with the assistance of aniline[J].Cataly Commun,2009,10:1725.
[45] Yu C L;Yu J C .A simple way to prepare C-N-codoped TiO2 photocatalyst with visible-light activity[J].Catalysis Letters,2009,129:462.
[46] Tryba B;Morawski AW;Inagaki M;Toyoda M .Effect of the carbon coating in Fe-C-TiO2 photocatalyst on phenol decomposition under UV irradiation via photo-Fenton process[J].Chemosphere: Environmental toxicology and risk assessment,2006(7):1225-1232.
[47] LvK L;Zuo H S;Sun J et al.(Bi,C and N) codoped TiO2 nanoparticles[J].Journal of Hazardous Materials,2009,161:396.
[48] Im, J.S.;Yun, S.-M.;Lee, Y.-S. .Investigation of multielemental catalysts based on decreasing the band gap of titania for enhanced visible light photocatalysis[J].Journal of Colloid and Interface Science,2009(1):183-188.
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