结构与组成可控、性能可调的微米-亚微米尺度的无机空心球具有极大的应用潜力.系统评述了胶粒模法和胶囊模法等无机空心球的硬模制备方法,阐述了硬模法在均相母液和非均相母液中的不同成壳机制,综述了硬模法制备无机空心球的相关应用及最新进展.
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