Synthesis and Structural Characterization of Erbium Complex with Tripodal Ligand, N, N, N′, N′, N″, N″-Hexaisopropyl-2, 2′, 2″-Nitrilotris (2,1-ethoxy) triacetamide (L)

稀土学报(英文版), 2002, 20(5): 378-381.

范军 ^1, , 刘伟生 ^2, , 唐宁 ^3, , 唐瑜 ^4, , 谭民裕 ^5, , 郁开北 ^6,

1.College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

2.College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

3.College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

4.College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

5.College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

6.Analysis and Measurement Center, Chengdu Branch of Chinese Science Academy, Chengdu 610041, China

基金项目: 国家自然科学基金(29871014)

Synthesis and Structural Characterization of Erbium Complex with Tripodal Ligand, N, N, N′, N′, N″, N″-Hexaisopropyl-2, 2′, 2″-Nitrilotris (2,1-ethoxy) triacetamide (L)

Keywords： rare earths

A new tripodal ligand, N, N, N′, N′, N″, N″-hexaisopropyl-2, 2′, 2″-nitrilotris (2,1-ethoxy)-triacetamide (L) and its new erbium picrate complex were prepared. The structure of the complex was determined by X-ray crystal structure analysis. The result reveals that the Er3+ is encapsulated by the three arms of the tripodal ligand, and nine-coordinated by the bridged-head nitrogen atom, all ether oxygen atoms and carbonyl oxygen atoms of the ligand, and two oxygen atoms of the bidentate picrate. The coordination polyhedron is a distorted mono-capped square antiprism.

参考文献

[1]	Su CY.;Liu HQ.;Wang QG.;Chen ZN.;Lu ZL.;Tong YX.;Mak TCW.;Kang BS. .Luminescent lanthanide complexes with encapsulating polybenzimidazole tripodal ligands[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,1999(7):1374-1375.
[2]	Sanada T;Suzuki T;Kaizaki S.Heterotrinuclear complexes containing d- and f-block elements: synthesis and structural characterization of novel lanthanide (Ⅲ)-nickel(Ⅱ)-lanthanide (Ⅲ) compounds bridged by oxamidate[J].Journal of the Chemical Society Dalton Transactions,1998:959.
[3]	Bretonnière Y;Mazzanti M;Wietzke R.Unprecedented self-assembly of M3L2trinuclear lanthanide complexes assisted by a flexible tripodal ligand containing terpyridine building units[J].Chemical Communications,2000:1543.
[4]	Wietzke R;Mazzanti M;Latour J M.Strong intromolecular π-π interactions favor the information of 2∶1(L∶ M) lanthanide complexes of tris(2-benzimidazolylmethyl)amine[J].Chemical Communications,1999:209.
[5]	Su Chengyong;Kang Beisheng;Mak T C W.Construction of two-and three- dimensional supramolecular networks with an encapsulated lanthanide (Ⅲ) complex as building block and hydrogen-bonded 4 4′-bipyridyl as spacer[J].Journal of the Chemical Society,Chemical Communications,1998:1551.
[6]	Tian Yongchi;Liang Yingqiu;Ni Jiazan .Syntheses and structure of rare earth picrate hydrates[J].Chemical Journal of Chinese Universities-Chinese,1988,9(09):113.
[7]	Speziale A J;Hamm P C .Preparation of new 2-chloroacetamide[J].Journal of the American Chemical Society,1956,78:2556.
[8]	Huang Shu;Yan Yunjiang;Tian Baozhi .Synthesis of diacylamide type acyclic crown ethers with bridged chains containing nitrogen and/or sulfur atoms[J].合成化学,1994,2(02):230.
[9]	Fan Liyan;Liu Weisheng;Tan Minyu et al.Synthesis crystal structure and fluorescence emission of complexes of lanthanide picrates with 2 2′-[1 2-phenylenebis(oxy)]bis (N N-diphenylacetamide) (PBD)[J].Polyhedron,2000,19:779.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Synthesis and Structural Characterization of Erbium Complex with Tripodal Ligand, N, N, N′, N′, N″, N″-Hexaisopropyl-2, 2′, 2″-Nitrilotris (2,1-ethoxy) triacetamide (L)

参考文献