欢迎登录材料期刊网

材料期刊网

高级检索

采用化学腐蚀方法在多晶硅表面制备多孔硅层,通过外吸杂热处理方法进行除杂后对腐蚀不同时间后多孔硅层的形貌、多晶硅少子寿命和电阻率等进行了研究。结果表明:随着腐蚀时间的延长,形成的多孔硅层呈现不同的形貌,多孔壁孔径逐渐变大,少子寿命延长且电阻率增大;腐蚀14min后。多孔硅层局部区域坍塌,孔壁变薄;腐蚀11min时,经850℃吸杂处理的多孔硅层少子寿命和电阻率达到峰值,分别为0.98μs和0.16Ω·cm。

Porous silicon layer was prepared on the surface of polycrystalline silicon by chemtcat etcnmg, The surface morphology, polycrystalline silicon minority carrier lifetime and resistivity of the porous silicon layers etched for different times were investigated after impurity removing by external gettering heat treatment. The results show that with the prolongation of etching time, the surface morphology of porous silicon layer was different, the pore diameter of the porous silicon got large gradually, the minority carrier lifetime and the resistivity were enhanced too. Some partial areas of porous silicon collapsed and the wall of holes turned thinner after etching for 14 min. The minority carrier lifetime and the resistivity of porous silicon reached 0. 98 μs and 0. 16 Ω·cm respectively after etching 11 min and gettering treatment at 850 ℃.

参考文献

[1] 郑春蕊,李艳,陈志耕,王程.多晶硅生产与产业发展概述[J].产业与科技论坛,2008(02):55-56.
[2] K. Morita;T. Miki .Thermodynamics of solar-grade-silicon refining[J].Intermetallics,2003(11/12):1111-1117.
[3] 邓海 .铸造多晶硅中原生杂质及缺陷的研究[D].浙江大学,2006.
[4] 魏奎先,戴永年,马文会,杨斌,于站良.太阳能电池硅转换材料现状及发展趋势[J].轻金属,2006(02):52-56.
[5] 谢荣国,席珍强,马向阳,袁俊,杨德仁.用化学腐蚀制备多孔硅太阳电池减反射膜的研究[J].材料科学与工程,2002(04):507-509,567.
[6] 朱琳,徐征,许颖,李海玲,王文静.多孔硅对多晶硅太阳电池中缺陷和杂质的吸除效应[J].太阳能学报,2004(02):259-262.
[7] 黄宜平,竺士炀,包宗明,何奕,钟回周,吴东平.多孔硅对硅中缺陷的吸除效应[J].半导体学报,1998(12):936.
[8] 王书荣,陈庭金,刘祖明,魏晋云,胡志华,廖华,李迎军.多晶硅太阳电池的吸杂实验研究[J].云南师范大学学报(自然科学版),2001(06):43-44.
[9] 夏玉山,陈一,宗祥福,李积和.软损伤吸杂作用机构的分析[J].固体电子学研究与进展,2000(02):223-228.
[10] 王海燕,卢景霄,郜晓勇,孙晓峰,段启亮.多孔硅形成机理的逆结晶学模型[J].人工晶体学报,2005(01):178-182.
[11] 王清涛,李清山,董艳锋,冀会辉.多孔硅的形成与理论分析[J].曲阜师范大学学报(自然科学版),2002(03):57-58,76.
[12] Drabczyk K.;Panek P.;Lipinski M. .The influence of porous silicon on junction formation in silicon solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(4):545-551.
[13] Strehlke S.;Levy-Clement C.;Bastide S. .Optimization of porous silicon reflectance for silicon photovoltaic cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1999(4):399-409.
[14] 黄宜平,郑大卫,李爱珍,汤庭鳌,崔堑,张翔九.多孔硅的微观结构及其氧化特性[J].半导体学报,1995(01):19.
[15] 张伟娜,谭毅,许富民.显微组织对冶金法制备多晶硅电阻率的影响[J].机械工程材料,2008(01):17-20.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%