普鲁士兰恒电流法沉积在聚苯胺膜上的性能表征

功能材料, 2008, 39(3): 507-514.

普鲁士兰恒电流法沉积在聚苯胺膜上的性能表征

马荣 ^1, , 刁训刚 ^2, , 张金伟 ^3, , 舒远杰 ^4,

1.北京航空航天大学,理学院,北京,100083

2.北京航空航天大学,理学院,北京,100083

3.北京航空航天大学,理学院,北京,100083

4.中国工程物理研究院,化工材料研究所,四川,绵阳,621900

基金项目: 中国工程物理研究院"双百"人才基金(2005R0504)

关键词：聚苯胺 , 普鲁士兰 , 傅立叶变换红外光谱 , 循环伏安 , PAMPS

Prussian blue electrodeposited on PANI based thin film for electrochromic device

在ITO玻璃上分别用循环扫描伏安法和恒电流法依次沉积了聚苯胺(PANI)和普鲁士兰(PB)薄膜,对PANI和PB单层膜及复合膜的红外光谱进行了分析,讨论了3种薄膜的循环伏安曲线和紫外-可见吸收光谱.结果表明,在所选沉积条件下,制备出了电活性高的电致变色复合薄膜,600nm处的着色效率η=57.3.用钾离子掺杂的聚(2-丙稀酰胺-2-甲基丙磺酸)(PAMPS)作为离子导体,电导率σ达到8.691×10-3S/cm,组装的器件循环50次后,CV曲线变化较小,性能稳定.

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普鲁士兰恒电流法沉积在聚苯胺膜上的性能表征

Prussian blue electrodeposited on PANI based thin film for electrochromic device

参考文献