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  将甲基丙烯酸丁酯(BMA)与聚醚酰亚胺(PEI)溶液混合,通过自由基聚合得到聚甲基丙烯酸丁酯/聚醚酰亚胺共混高分子体系(PBMA/PEI);将PBMA/PEI作为有机功能层制备三明治结构的阻变存储器件ITO/(PBMA/PEI)/Ag,对PBMA/PEI进行结构表征,分析其热性能和ITO/(PBMA/PEI)/Ag的阻变性能。结果表明:制备的PBMA/PEI具有良好的耐热性能,其初始分解温度为250℃;制备的阻变存储器件具有较好的阻变存储特性,即较高的电流开关比(106)、较低的跳变电压(1.8 V)、较低的开态电流(约为10-4 A)。

A poly(butyl methacrylate)(PBMA)/polyetherimide(PEI) blending polymer was synthesized by rad-ical polymerization from butyl methacrylate(BMA) and polyetherimide solution, and a sandwich structure resistive random access memory ITO/(PBMA/PEI)/Ag was prepared using PBMA/PEI as organic function layer. The structure of the PBMA/PEI was characterized and the heat-resistance and resistive switching characteristics of the ITO/(PBMA/PEI)/Ag were studied. The results show that the PBMA/PEI has good heat-resistance, with the initial decomposition temperature of 250℃. The resistive random access memory has good resistive switching characteristics, that means higher Ion/Ioff ratio(106), lower switching threshold voltage (1.8 V) and lower on-current (about 10-4 A).

参考文献

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[6] Dong Wang;Hua Li;Najun Li;Ying Zhao;Oianhao Zhou;Oingfeng Xu;Jianmei Lu;Lihua Wang .A new DRAM-type memory devices based on polymethacrylate containing pendant 2-methylbenzothiazole[J].Materials Chemistry and Physics,2012(1):273-278.
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