将纳米掺锑二氧化锡(ATO)粒子经过超声分散和偶联剂处理后,以甲基丙烯酸甲酯(MMA)为单体,用原位聚合法制备了纳米ATO/PMMA乙醇分散液.讨论了偶联剂种类、MMA与ATO质量比值,引发剂偶氮二异丁腈(AIBN)用量对纳米ATO/PMMA乙醇分散液分散稳定性的影响.确定了合适的偶联剂为乙烯基三叔丁基过氧硅烷(VTPS),最优工艺参数为m(MMA):m(ATO)=2,w(AIBN)=1.5%.往聚丙烯酸酯树脂加入该纳米ATO/PMMA乙醇分散液所制得的涂料,其涂膜同时具有良好的可见光透过率和近红外光阻隔性能.
A nano-ATO/PMMA ethanol dispersion solution was prepared by in-situ polymerization with methyl meth-acrylate (MMA) as monomer and nano-ATO (antimony doped tin oxide) treated with ultrasonic and coupling agent as filler.The effect of categories of coupling agent, mass ratio of MMA to ATO and content of azobisisobutyronitrile (AIBN, an initiator) on stability of nano-ATO/PMMA ethanol dispersion solution were studied. The optimal coupling agent was determined as vinyltris(tert-butylperoxy)silane (VTPS) and process parameters were optimized as follows: m (MMA) / m (ATO) = 2 and w (AIBN) = 1.5%. The film obtained from coating containing polyacrylate resin and nano-ATO/PMMA ethanol dispersion solution has good properties of visible light transmittance and near-infrared light barrier.
参考文献
| [1] | CHOPRA K L;MAJOR S;PANDYA D K .Transarent conductors-A status review[J].Thin Solid Films,1983,102(l):1-46. |
| [2] | GARCiA-CANADAS J;MEACHAM A P;PETER L M et al.A near-infrared electrochromic window based on an Sb-doped SnO2 electode modified with a Ru-dioxolene complex[J].Angewandte Chemie International Edition,2003,42(26):3011-3014. |
| [3] | 纳米ATO粉体表面改性研究[J].中国涂料,2005(10):21-22,28. |
| [4] | 肖明艳,陈建敏.有机-无机杂化材料研究进展[J].高分子材料科学与工程,2001(05):6-10. |
| [5] | 徐珊珊,王世敏,许祖勋,董兵海,孙文兵.纳米粒子的表面聚合物接枝改性[J].化工新型材料,2005(04):44-46. |
| [6] | Duguet E.;Morvan F.;Maheu P.;Fontanille M.;Abboud M. .PMMA encapsulation of alumina particles through aqueous suspension polymerisation processes[J].Macromolecular symposia,2000(0):365-370. |
| [7] | 黄艳,陈国栋,邹其超,武利民.纳米SiO2复合水性丙烯酸树脂的制备及形态研究[J].中国涂料,2005(01):30-32. |
| [8] | 聂王焰,李洋,周艺峰,倪士宝.单分散甲基丙烯酸甲酯-苯乙烯共聚物微球的制备与表征[J].涂料工业,2008(11):4-7. |
| [9] | 沈新璋,金名惠.甲基丙烯酸对纳米SiO2微粒表面的原位聚合改性[J].应用化学,2003(10):1003-1005. |
| [10] | 李玉,于文志,韩兆让,刘春丽,余娜,崔琳琳.PMMA/TiO2-SiO2高分子杂化材料的制备与表征[J].高分子材料科学与工程,2008(11):161-164. |
| [11] | 董先明,罗颖,张淑婷,符若文,章明秋.原位聚合法制备炭黑/聚甲基丙烯酸酯导电复合材料[J].高分子材料科学与工程,2007(03):43-46. |
| [12] | 许新,李秀艳,王高升.颜料对太阳热反射涂层热反射性能的影响[J].现代涂料与涂装,1998(04):3. |
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