分析了"卤化氰-酚法"合成氰酸酯单体的化学原理.根据实际的操作过程,将"卤化氰-酚法"划分为"活性酚氧离子"路线和"活性氰"路线,讨论了其可能的反应机理.评述了高纯度和高收率氰酸酯单体合成的新进展,以及国内氰酸酯单体工业合成的现状.
参考文献
| [1] | Grigat E;Cologne-Stammheim;Putter R .Esters of cyanic acid[P].GP 39039,1963. |
| [2] | Fang T;Shimp D A .Polycyanurate esters:science and applications[J].Progress in Polymer Science,1995,20(01):61. |
| [3] | Nair C P R;Mathew D;Ninan K N .Cyanate ester resins,recent developments[J].Advances in Polymer Science,2001,155:1. |
| [4] | 王汝敏,蓝立文.先进复合材料用热固性树脂基体的发展[J].热固性树脂,2001(01):36-38. |
| [5] | 闰福胜;王志强;张明习.双酚A氰酸酯树脂的合成与性能研究[A].合肥:中国科学技术大学出版社,2000:28. |
| [6] | Snow A W.The synthesis,manufacture and characterization of cyanate ester monomers[A].Glasgow:Chapman and Hall,Blackie Academic & Professional,1994:7. |
| [7] | 闫福胜.氰酸酯树脂研究[M].西安:西北工业大学,1999 |
| [8] | Masaharu D .Production of cyanate group-containing phenolic resin[P].JP 59149918,1984. |
| [9] | Das S;Ridge B .Process for making cyanto containing phenolic resins[P].US 5137989,1992. |
| [10] | 邢其毅;徐瑞秋;周政.基础有机化学[M].北京:高等教育出版社,1994 |
| [11] | Grigat E;Cologne-Stammheim;Schminke H D et al.Phenolic resins containing cyanate ester groups[P].US 3448079,1969. |
| [12] | Mineaki T;Susumu M;Kazuo N .Cyanato-group-containing phenol resin[P].US 4022755,1977. |
| [13] | Bedwell W B;Swedo R J;DeBona B T et al.Process for the production of cyanate ester resins having unique composition[P].US 5756592,1998. |
| [14] | Simon S L;Gillham J K .Cure kinetics of a thermosetting liquid dicyanate ester/high-Tg polycyanurate material[J].Journal of Applied Polymer Science,1993,47:461. |
| [15] | Pascault J P;Galy J;Mechin F.Additives and modifiers for cyanate ester resins[A].Glasgow:Chapman and Hall,1994:116. |
| [16] | Satoshi O;Hisashi W .Manufacture of high purity aromatic cyanate ester[P].JP 1l255734,1999. |
| [17] | Satoshi O;Hisashi W .Manufacture of aromatic cyanate ester in high yield[P].JP 11255735,1999. |
| [18] | 李文峰.改进的卤化氰-酚法合成氰酸酯研究[M].西安:西北工业大学,2004 |
| [19] | 李文峰,梁国正,王志强,轩立新,冯青平,陈淳.改进的酚-溴化氰法合成酚醛型氰酸酯及其表征[J].航空学报,2004(04):406-410. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%