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对Fe-C合金贝氏体在奥氏体贫碳区形成机制进行了热力学分析.结果表明,贝氏体相变驱动力随奥氏体贫碳区含碳量的降低而增加;在Bs温度,贝氏体临界相变驱动力(绝对值)为470─1200J/mol,随合金含碳量的增加而增加;贝氏体铁素体初始含碳量为部分过饱和碳,其过饱和程度随相变温度的降低而增加,且相变驱动力亦相应升高.在整个贝氏体转变温区,初期贝氏体在奥氏体贫碳区马氏体式切变形成具有热力学可能性.

Thermodynamic analysis for shear formation of bainitic ferrite in carbon-depleted regions of austenite is conducted. The driving force of bainitic formation in carbon-depleted region increases with the reduction of carbon concentration in this region and can overcome the energy resistance. The critical driving force (absolute value) at Bs temperature is 470─1200 J/mol. The freshly-formed bainitic ferrite is with partial supersaturation of carbon, which increases with decreasing the reaction temperature. Finally,it is concluded that the shear mechanism of bainitic formation in carbon-depleted region is thermodynamically feasible within the whole temperature range of bainitic reaction.

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