研究压铸AlMg5Si2Mn合金的电化学腐蚀、晶间腐蚀和腐蚀疲劳机理.结果表明:合金的自腐蚀电位和点蚀电位分别为-1220和-690mV,钝化区间约为530mV,说明合金的耐腐蚀性能良好.合金的晶间腐蚀倾向明显,这主要是由于Mg2Si相自腐蚀电位较低,且(Al+Mg2Si)共晶区的体积分数较大(29.6%).电化学腐蚀反应和Mg2Si自身溶解产生的氢元素导致疲劳试样表面发生阳极溶解,加速了疲劳裂纹的萌生,从而显著降低了合金的疲劳寿命.腐蚀疲劳试样的裂纹主要是沿晶界扩展.氢元素也导致合金塑性下降,造成应力腐蚀开裂.
参考文献
[1] | Alan A.Luo,Anil K.Sachdev,Bob R.Powell.Advanced casting technologies for lightweight automotive applications[J].中国铸造,2010(04):463-469. |
[2] | 左宏志,刘昌明,邹茂华,谷忠明,范增,李德全,吴均.ZL112Y压铸铝合金摩托车零件的半固态高压铸造成形[J].中国有色金属学报,2003(04):949-955. |
[3] | YUAN Xiao-guang,HUANG Hong-jun,LI Rong-de,CAO Yang,SU Shi-fang.Die Casting Technology Develops Steadily——A Commentary on the 5th China International Die Casting Congress[J].中国铸造,2006(04):322-324. |
[4] | COLE G S;SHERMAN A M .Light weight materials for automotive applications[J].Materials Characterization,1995,35(01):3-9. |
[5] | KAUFMANN H;UGGOWITZER P J.Metallurgy and processing of high-integrity light metal pressure castings[M].Berlin:Schiele & Sch(o)n,2007 |
[6] | OTARAWANNA S;GOURLAY C M;LAUKLI H I;DAHLE A K .Microstructure formation in AlSi4MgMn and AlMg5Si2Mn high-pressure die castings[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,2009,40(07):1645-1659. |
[7] | HIELSCHER U .New diecasting alloy with good mechanical properties without heat treatment[J].Fonderia (Italy),1999,48(11/12):33-36. |
[8] | Li Wan;Zuqi Hu;Shusen Wu;Xueqiang Liu.Mechanical properties and fatigue behavior of vacuum-assist die cast AlMgSiMn alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2013:252-258. |
[9] | 胡祖麒,万里,吴晗,刘学强,邹广,吴树森.高强韧压铸Al-Mg-Si-Mn合金的微观组织及力学性能[J].中国有色金属学报,2013(03):616-622. |
[10] | JOHANNESSON B;C(A)CERES C H .Effect of Si additions and heat treatment on the mechanical behaviour of an Al-5Mg cast alloy[J].International Journal of Cast Metals Research,2004,17(02):94-98. |
[11] | GREVEN K;DRAGULIN D.Ductile high pressure die casting-Heat treated or temper F[A].LKR:Verlag,2005 |
[12] | Seong-Jong KIM,Seok-Ki JANG,Min-Su HAN,Jae-Cheul PARK,Jae-Yong JEONG,Sang-Ok CHONG.船用5052-O铝合金在海水中的力学和电化学性能[J].中国有色金属学报(英文版),2013(03):636-641. |
[13] | VARGEL C.Corrosion of aluminum[M].New York:Elsevier Science Publishing Company,2004:96-108. |
[14] | 曾锋利,卫中领,李劲风,李朝兴,谭星,张昭,郑子樵.Al-Mg-Si合金中Mg2Si和Si粒子在晶间腐蚀过程中的作用机理[J].中国有色金属学报(英文版),2011(12):2559-2567. |
[15] | HOLTZ R;PAO P;BAYLES R;LONGAZEL T GOSWAMI R .Corrosion-fatigue behavior of aluminum alloy 5083-H131 sensitized at 448 K (175 ℃)[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,2012,43(08):2839-2849. |
[16] | ABALLE A;BETHENCOURT M;BOTANA F J;CANO M J MARCOS M .Influence of the cathodic intermetallics distribution on the reproducibility of the electrochemical measurements on AA5083 alloy in NaCl solutions[J].Corrosion Science,2003,45(01):161-180. |
[17] | AMBAT R;AUNG N N;ZHOU W .Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy[J].Corrosion Science,2000,42(08):1433-1455. |
[18] | 张莉,王渠东,胡茂良,丁文江.Al-Si-Cu压铸铝合金的耐腐蚀性能[J].特种铸造及有色合金,2011(11):1021-1024. |
[19] | Kiryl A. Yasakau;Mikhail L. Zheludkevich;Sviatlana V. Lamaka;Mario G. S. Ferreira .Role of intermetallic phases in localized corrosion of AA5083[J].Electrochimica Acta,2007(27):7651-7659. |
[20] | SURESH S.Fatigue of structures and materials[M].New York:Cambridge University Press,1991:362-369. |
[21] | 胡祖麒,万里,吴晗,刘学强,邹广,吴树森.时效处理对高强韧压铸Al-Mg-Si-Mn合金力学性能的影响[J].铸造,2013(01):13-16,20. |
[22] | MEYN D A .Fractographic diagnosis of stress corrosion cracking in Al-Zn-Mg alloys[J].CORROSION,1970,26(10):427-429. |
[23] | Srivatsan TS;Menzemer C .The effect of environment on fatigue crack growth behavior of aluminum alloy 5456[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,1999(1/2):188-195. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%