In high speed continuous casting of peritectic steel slabs, mold fluxes with high basicity are required for less surface defect product. However, the basicity of remaining liquid slag film tends to decrease in casting process because of the crystallization of 3CaO ·2SiO2 · CaF2. Thus, a way is put forward to improve mold fluxesr properties by raising the original basicity. In order to confirm the possibility of this method, the effect of rising original basicity on the properties of mold fluxes is discussed. Properties of high fluorine based mold fluxes with different basicities and contents of CaF2 , Na2 O, and MgO were measured, respectively. Then, properties of higher basicity mold fluxes were discussed and compared with traditional ones. The results show that increasing the basicity index can improve the melting and flow property of mold fluxes. With the increasing basicity, crystallization rate of mold fluxes increases obviously and crystallization temperature tends to decrease when the basicity exceeds 1.35. The method presen- ted before is proved as a potential way to resolve the contradiction between horizontal heat transfer controlling and solidified shell lubricating for peritectic steel slab casting. But further study on improving the flow property of liquid slag is needed. This work can be used to guide mold fluxes design for high speed continuous casting of peritectic steel slabs.
参考文献
[1] | CHI Jing-hao;GAN Yong-nian.Mould Powder for Continuous Casting[M].沈阳:东北大学出版社,1992 |
[2] | A. Yamauchi;K. Sorimachi;I. Yamauchi .Effect of solidus temperature and Crystalline phase of mould flux on heat transfer in continuous Casting mould[J].Ironmaking & Steelmaking: Products and applications,2002(3):203-207. |
[3] | Mills K C;Fox A B .The Role of Mold Fluxes in Continuous Casting-So Simple Yet So Complex[J].ISIJ International,2003,43(10):1479. |
[4] | J. A. Kromhout;C. Liebske;S. Melzer .Mould powder investigations for high speed casting[J].Ironmaking & Steelmaking,2009(4):291-299. |
[5] | MO De-min;ZHANG Ya-li .Break Temperatures of Mold Flu xes and Their Relevance to Continuous Casting[J].Wide andHeavy Plate,2002,8(04):40. |
[6] | Nakano T;Kishi T;Koyama K et al.Mold Powder Technolo- gy for Continuous Casting of Aluminum-Killed Steel[J].ISIJ International,1984,12(11):950. |
[7] | Park J H;Min D J .The Effect of CaF2 on the Viscosities and Structures of CaO-SiO2(-MgO)-CaF2 Slags[J].Metallurgical and Materials Transactions,2002,33B(10):723. |
[8] | 舒俊,金山同,张丽,曹卫文,宋任波,王向光.连铸结晶器保护渣结晶温度[J].北京科技大学学报,2000(06):508-511. |
[9] | Sanchez-Jimenez PE;Criado JM;Perez-Maqueda LA .Kissinger kinetic analysis of data obtained under different heating schedules[J].Journal of thermal analysis and calorimetry,2008(2):427-432. |
[10] | Boswell P G .On the Calculation of Activation Energies Using a Modified Kissinger Method[J].Journal of Thermal Analy- sis,1980,18:353. |
[11] | Budrugeac P;Segal E .Applicability of the Kissinger Equation in Thermal Analysis[J].Journal of Thermal Analysis and Calorimetry,2007,88(03):703. |
[12] | MAO Yu-wen.Metallurgy Fluxes[M].北京:冶金工业出版社,1994 |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%