采用化学气相沉积工艺在炭纤维表面生长了碳纳米管,并观察了它的微观形貌,且对其影响因素进行了初步研究.结果表明:纤维表面的纵向沟槽可以负载催化剂粒子,是生长碳纳米管的物理基础;催化剂的浓度太高,金属粒子容易团聚长大,所得碳纳米管的管径较大;而催化剂浓度太低,则不能在炭纤维整个表面均匀生长碳纳米管;最佳的催化剂溶液的浓度是0.05mol/L的硝酸钴.比较了铁、钴、镍三种过渡金属催化剂,从形成的碳纳米管的质量来看,钴催化剂最佳.
参考文献
| [1] | 赵稼祥,王曼霞.复合材料用高性能炭纤维的发展和应用[J].新型炭材料,2000(01):68-75. |
| [2] | 夏春霞,闫亚明,邓蜀平,白光君,蒋云峰,宋惠森,王钰.PAN基炭纤维经济规模分析[J].新型炭材料,2001(04):58-62. |
| [3] | 李峰,白朔,成会明.纳米碳管[J].新型炭材料,2000(03):79-80. |
| [4] | B. O. Boskovic;V. B. Golovko;M. Cantoro .Low temperature synthesis of carbon nanofibres on carbon fibre matrices[J].Carbon,2005(13):2643-2648. |
| [5] | Zhang M;Atkinson KR;Baughman RH .Multifunctional carbon nanotube yarns by downsizing an ancient technology[J].Science,2004(5700):1358-1361. |
| [6] | Downs W B;Baker R T K .Novel carbon fiber-carbon filament structures[J].CARBON,1991,29(08):1173-1179. |
| [7] | Downs WB.;Baker RTK. .MODIFICATION OF THE SURFACE PROPERTIES OF CARBON FIBERS VIA THE CATALYTIC GROWTH OF CARBON NANOFIBERS[J].Journal of Materials Research,1995(3):625-633. |
| [8] | E. T. Thostenson;W. Z. Li;D. Z. Wang;Z. F. Ren;T. W. Chou .Carbon nanotube/carbon fiber hybrid multiscale composites[J].Journal of Applied Physics,2002(9):6034-6037. |
| [9] | Shen Zhu;Ching-Hua Su;S.L.Lehoczky;I.Muntele;D.Ila .Carbon nanotube growth on carbon fibers[J].Diamond and Related Materials,2003(10/11):1825-1828. |
| [10] | Ci L J;Zhao Z G;Bai J B .Direct growth of carbon nanotubes on the surface of ceramic fibers[J].Carbon,2005,43:883-894. |
| [11] | Zhao Z G;Ci L J;Cheng H M et al.The growth of multi-walled carbon nanotubes with different morphologies on carbon fibers[J].Carbon,2005,43:663-673. |
| [12] | 许并社,张春一,杨永珍,刘旭光,罗秋苹.FeCl3催化生长脱油沥青基气相生长炭纤维[J].新型炭材料,2007(03):193-198. |
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