采用常流脉冲控制方式于(NaPO3)6-NaF-NaAlO2溶液中用微弧氧化法在Ti6Al4V表面制备了陶瓷化涂层, 研究了涂层的生长过程及组织结构变化.结果表明: 氧化过程中涂层的生长经历了由快到慢的过程, 在前10min涂层以较快速度生长(约3μm/min), 随着时间的延长涂层生长速度逐渐减慢; 生长过程中涂层表面微孔数目减少, 微孔孔径增大, 涂层表面气孔率增大; 涂层主要由二氧化钛的两种不同变体(锐钛矿及金红石)以及磷化物相AlPO4组成; 随着氧化的进行, 锐钛矿含量降低, 金红石含量增加, 氧化过程中发生了锐钛矿相到金红石相的相转变; 结晶AlPO4相是通过水合多聚磷酸铝在放电区附近发生高温热解反应而进入涂层.
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