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为了建立可靠的燃料替代模型,本文选择了正癸烷以及甲苯作为链烷烃与芳香烃的代表,系统研究了这两种燃料混合物的非稳态着火过程,分析了燃料中甲苯含量以及标量扩散率对着火延迟时间的影响。研究结果显示,较大的甲苯含量以及标量扩散率都会增加系统的着火延迟时间。文中揭示了由甲苯含量变化导致的化学反应特性以及由拉伸率变化导致的输运特性对着火过程的影响。

In order to develop reliable surrogate fuel models, n-decane and toluene were chosen as the representatives of alkanes and aromatic hydrocarbons respectively. The unsteady ignition process of these two fuels was systematically investigated. The effects of toluene addition and scalar dissipation rate on the ignition delay time were analyzed. It was found that the toluene addition and dissipation rate both increase the ignition delay time. Moreover, the present work demonstrated the chemical effects due to toluene addition and the transport effects related to stretch rate on the ignition process.

参考文献

[1] Colin Ellis;Michael S. Scott;Raymond W. Walker .Addition of toluene and ethylbenzene to mixtures of H_2 and O_2 at 772 K: Part 2: Formation of products and determination of kinetic data for H+ additive and for other elementary reactions involved[J].Combustion and Flame,2003(3):291-304.
[2] MARCOS CHAOS;ANDREI KAZAKOV;ZHENWEI ZHAO .A High-Temperature Chemical Kinetic Model for Primary Reference Fuels[J].International Journal of Chemical Kinetics,2007(7):399-414.
[3] Kinetic effects of toluene blending on the extinction limit of n-decane diffusion flames[J].Combustion and Flame,2010(3):411.
[4] Shiling Liu;John C. Hewson;Jacqueline H. Chen;Heinz Pitsch .Effects of strain rate on high-pressure nonpremixed n-heptane autoignition in counterflow[J].Combustion and Flame,2004(3):320-339.
[5] Ju YG.;Maruta K.;Liu FS.;Guo HS. .ON THE EXTINCTION LIMIT AND FLAMMABILITY LIMIT OF NON-ADIABATIC STRETCHED METHANE-AIR PREMIXED FLAMES[J].Journal of Fluid Mechanics,1997(0):315-334.
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