欢迎登录材料期刊网

材料期刊网

高级检索

可见光响应范围窄和量子效率低是导致TiO<,2>纳米管光催化活性低的两个主要因素,而用微量的金属元素取代TiO<,2>晶格里的钛,通过调整其能带结构,改变电子-空穴复合率和界面电子转移速度,可提高TiO<,2>在可见光下的催化活性.综述了近年来利用金属掺杂提高光催化效率的研究成果,并指出目前存在的问题,对今后的研究提出了展望.

参考文献

[1] Kim S;Hong S .Kinetic study of photoeatalytic degradation of volatile organic compound in air using thin film TiO2 photocatalyst[J].Applied Catalysis B:Environmental,2002,35(04):305.
[2] Testa J J;Grela M A;Litter M I .Experimental evidence in favor of an initial one-electron-transfer process in the heterogeneous photocatalytie reduction of chromium (VI) over TiO2[J].Langmuir,2001,17(12):3515.
[3] Han TY;Wu CF;Hsieh CT .Hydrothermal synthesis and visible light photocatalysis of metal-doped titania nanoparticles[J].Journal of Vacuum Science & Technology, B. Microelectronics and Nanometer Structures: Processing, Measurement and Phenomena,2007(2):430-435.
[4] Srimala Sreekantan;Lai Chin Wei .Study on the formation and photocatalytic activity of titanate nanotubes synthesized via hydrothermal method[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1/2):436-442.
[5] Lee Kheng Tan;Manippady K. Kumar;Wen Wen An .Transparent, Well-Aligned TiO2 Nanotube Arrays with Controllable Dimensions on Glass Substrates for Photocatalytic Applications[J].ACS applied materials & interfaces,2010(2):498-503.
[6] M. Alam Khan;Do Hung Han;O.-Bong Yang .Enhanced Photoresponse Towards Visible Light In Ru Doped Titania Nanotube[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(6):3687-3690.
[7] TiO_2 nanotubes incorporated with CdS for photocatalytic hydrogen production from splitting water under visible light irradiation[J].International journal of hydrogen energy,2010(13):7073-7079.
[8] Shrestha, NK;Yang, M;Nah, YC;Paramasivam, I;Schmuki, P .Self-organized TiO2 nanotubes: Visible light activation by Ni oxide nanoparticle decoration[J].Electrochemistry communications,2010(2):254-257.
[9] Yang L X;Xiao Y;Liu S H et al.Photocatalytic reduction of Cr(Ⅵ) on WO《,3》 doped long TiO2 nanotube arrays in the presence of citric acid[J].Applied Catalysis B:Environmental,2010,94(1-2):142.
[10] 王泽高,郑树楠,贾春阳,延卫.Cu掺杂TiO2及其纳米管的制备、表征与光催化性能[J].无机化学学报,2010(05):875-878.
[11] 李静,孙岚,庄惠芳,王成林,杜荣归,林昌健.铁掺杂TiO2纳米管阵列制备及其光电化学性质[J].电化学,2008(02):213-217.
[12] Han Yang;Chunxu Pan .Synthesis of carbon-modified TiO_2 nanotube arrays for enhancing the photocatalytic activity under the visible light[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1):L8-L11.
[13] Photoelectrochemical property and photocatalytic activity of N-doped TiO_2 nanotube arrays[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2010(13):p.4397.
[14] 刘守新;刘鸿.光催化及光电催化基础与应用[M].北京:化学工业出版社,2006:80.
[15] Sun, L;Li, J;Wang, CL;Li, SF;Chen, HB;Lin, CJ .An electrochemical strategy of doping Fe3+ into TiO2 nanotube array films for enhancement in photocatalytic activity[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2009(10):1875-1880.
[16] Preparation of Fe-doped TiO_2 nanotube arrays and their photocatalytic activities under visible light[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2010(2):224.
[17] Xiaobo Chen;Samuel S. Mao .Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications[J].Chemical Reviews,2007(7):2891-2959.
[18] Li H B;Duan X C;Liu G C et al.Synthesis and characterization of copper ions surface-doped titanium dioxide nanotubes[J].Materials Research Bulletin,2008,43(8-9):1971.
[19] 颜欣,刘中清,李丹丹,李纲.铜掺杂TiO2纳米管阵列的制备与光催化还原性能[J].功能材料,2010(07):1278-1281.
[20] Chien-Te Hsieh;Wen-Syuan Fan;Wei-Yu Chen .Adsorption and visible-light-derived photocatalytic kinetics of organic dye on Co-doped titania nanotubes prepared by hydrothermal synthesis[J].Separation and Purification Technology,2009(3):312-318.
[21] 王竹梅,李月明,夏光华,陈云霞,左建林.钴掺杂TiO2纳米管阵列的制备及其光催化性能研究[J].陶瓷学报,2009(03):300-303.
[22] 赵慧敏,陈越,全燮,阮修莉.Zn掺杂TiO2纳米管电极制备及其对五氯酚的光电催化降解[J].科学通报,2007(02):158-162.
[23] Wilke K;Breuer H D .The influence of transition metal doping on the physical and photocatalytic properties of titania[J].Journal of Photochemistry and Photobiology A: Chemistry,1999,121(01):49.
[24] 栾勇,傅平丰,戴学刚,杜竹玮.金属离子掺杂对TiO2光催化性能的影响[J].化学进展,2004(05):738-746.
[25] Li XZ.;Li FB. .Study of Au/Au3+-TiO2 photocatalysts toward visible photooxidation for water and wastewater treatment[J].Environmental Science & Technology: ES&T,2001(11):2381-2387.
[26] 刘国光,郭小阳,郑立庆,李维,毛小权,娄淑芳,张治军.Zr\TiO2纳米管的制备及其光催化活性的初步研究[J].环境科学学报,2008(04):710-713.
[27] Liu, HJ;Liu, GG;Zhou, QX .Preparation and characterization of Zr doped TiO2 nanotube arrays on the titanium sheet and their enhanced photocatalytic activity[J].Journal of Solid State Chemistry,2009(12):3238-3242.
[28] LiuG G;Zhang X Z;Xu Y J et al.The preparation of Zn《'2+》-doped TiO2 nanoparticles by sol-get and solid phase reaction methods respectively and their photocatalytic acti-vi-ties[J].Chemosphere,2005,59(09):1367.
[29] Chang SM;Doong RA .Characterization of Zr-doped TiO2 nanocrystals prepared by a nonhydrolytic sol-gel method at high temperatures[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(42):20808-20814.
[30] Lukac J;Klementova M;Bezdicka P;Bakardjieva S;Subrt J;Szatmary L;Bastl Z;Jirkovsky J .Influence of Zr as TiO2 doping ion on photocatalytic degradation of 4-chlorophenol[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(1/2):83-91.
[31] Liu, H.;Liu, G.;Shi, X. .N/Zr-codoped TiO_2 nanotube arrays: Fabrication, characterization, and enhanced photocatalytic activity[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2010(1/3):35-40.
[32] E. Setiawati;K. Kawano .Stabilization of anatase phase in the rare earth; Eu and Sm ion doped nanoparticle TiO_2[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2008(1/2):293-296.
[33] 王振阳,何洪,戴洪兴,訾学红,王亮,薛彬.稀土掺杂TiO2光催化的研究进展[J].中国稀土学报,2006(z2):94-99.
[34] 钱斯文,王智宇,王民权.La3+掺杂对纳米TiO2微观结构及光催化性能的影响[J].材料科学与工程学报,2003(01):48-52.
[35] Ranjit K T;Willne I;Bossmann S H et al.Lanthanide oxide doped titanium dioxide photocatalysts:Effctive photocatalysts for the enhanced degradation of salicylic acid and tcinnamic acid[J].Journal of Catalysis,2001,204(02):305.
[36] 薛寒松,李华基,胡慧芳,陈永盛.镧掺杂二氧化钛纳米管光催化性能[J].中国稀土学报,2008(01):18-23.
[37] 薛寒松,李华基,易于,胡慧芳,孟翠.铈掺杂二氧化钛纳米管的光催化性能[J].机械工程材料,2008(06):36-39,65.
[38] Preparation, characterization and photocatalytic activity of the neodymium-doped TiO_2 nanotubes[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(20):8648-8653.
[39] Tu Y F;Huang S Y;Sang J P et al.Synthesis and photocatalytic properties of Sn-doped TiO2 nanotube arrays[J].Journal of Alloys and Compounds,2009,482(1-2):382.
[40] 龙绘锦,王恩君,董江舟,王玲玲,曹永强,杨文胜,曹亚安.In离子掺杂二氧化钛纳米管可见光催化活性的研究[J].化学学报,2009(14):1533-1538.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%