热电材料是一种能将热能和电能直接相互转换的功能材料.热电器件由于具有结构简单、低价环保、无噪声、使用寿命长等优点,被人们广泛应用在温差发电与半导体制冷技术中.Zn-Sb合金由于其优越的热电性能成为了现阶段最重要的热电材料之一,以ZnSb、Zn4 Sb3两种合金最为常见.新近发现的Zn8Sb7结构,成为了新的研究热点.主要针对常见Zn-Sb合金的晶体结构、性能、制备技术进行了总结,并展望了该材料的应用前景.
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