全钒液流电池(VRB)作为一种大规模的蓄电储能设备,在新能源发电和电网调峰等方面有重要应用.质子传导膜是钒电池的关键材料,对电池的性能、成本和寿命有着十分重要的影响.文章在简单介绍VRB的基本组成和原理以及对隔膜的性能要求的基础上,主要论述了目前报道的几种VRB隔膜材料及其改性方法,以及对电池性能的影响,最后对质子交换膜的发展方向和前景进行了总结和展望.
参考文献
| [1] | Yang, Z.;Zhang, J.;Kintner-Meyer, M.C.W.;Lu, X.;Choi, D.;Lemmon, J.P.;Liu, J. .Electrochemical energy storage for green grid[J].Chemical Reviews,2011(5):3577-3613. |
| [2] | Bruce Dunn;Haresh Kamath;Jean-Marie Tarascon .Electrical Energy Storage for the Grid: A Battery of Choices[J].Science,2011(Nov.18 TN.6058):928-935. |
| [3] | Sum E;Rychcik M;Skyllas-KKazacos M .Investigation of the V(Ⅱ)/V(Ⅲ) system for use in the positive halfcell of a redox battery[J].Journal of Power Sources,1985,16(02):85-95. |
| [4] | Sum E;Skyllas-Kazacos M .A study of the V(Ⅱ)/V (Ⅲ) redox couple for redox flow cell applications[J].Journal of Power Sources,1985,15(23):179-190. |
| [5] | Mohammadi T.;Skyllaskazacos M. .CHARACTERISATION OF NOVEL COMPOSITE MEMBRANE FOR REDOX FLOW BATTERY APPLICATIONS[J].Journal of Membrane Science,1995(1/2):77-87. |
| [6] | Ping Zhao;Huamin Zhang;Hantao Zhou .Characteristics and performance of 10 kW class all-vanadium redox-flow battery stack[J].Journal of Power Sources,2006(2):1416-1420. |
| [7] | Skyllas-Kazacos M;Kasherman D;Hong D R et al.Charaeteristies and performance of 1kW UNSW vanadium redox battery[J].power Source,1991,35(04):399-404. |
| [8] | 张华民.高效大规模化学储能技术研究开发现状及展望[J].电源技术,2007(08):587-591. |
| [9] | M. H. Chakrabarti;R. A. W. Dryfe;E. P. L. Roberts .Evaluation of electrolytes for redox flow battery applications[J].Electrochimica Acta,2007(5):2189-2195. |
| [10] | 文越华,张华民,钱鹏,衣宝廉.离子交换膜全钒液流电池的研究[J].电池,2005(06):414-416. |
| [11] | 王保国.新能源领域的质子交换膜研究与应用进展[J].膜科学与技术,2010(01):1-8. |
| [12] | Li Xianfeng;Zhang Huamin;Mai Zhensheng et al.Ion exchange membranes for vanadium redox flow battery applications[J].Energy & Environ Sci,2011,4(04):1147-1160. |
| [13] | Schwenzer B;Zhang Jianlu;Kim S et al.Membrane development for vanadium redox flow batteries[J].Chem Sus Chem,2011,4(10):1388-1406. |
| [14] | 黄倬;屠海令.质子交换膜燃料电池的研究开发与应用[M].北京:冶金工业出版社,2000:88-96. |
| [15] | Xi Jingyu;Wu Zenghua;Qiu Xinping et al.Nafion SiO2 hybrid membrane for vanadium redox flow battery[J].Journal of Power Sources,2007,166(02):531-536. |
| [16] | Xiangguo Teng;Yongtao Zhao;Jingyu Xi;Zenghua Wu;Xinping Qiu;Liquan Chen .Nafion/organically Modified Silicate Hybrids Membrane For Vanadium Redox Flow Battery[J].Journal of Power Sources,2009(2):1240-1246. |
| [17] | 柳东东,林茂才,管涛,余晴春.全钒氧化还原液流电池Nafion/SiO2复合膜的研究[J].电化学,2010(04):455-459. |
| [18] | Sang SB;Wu QM;Huang KL .Preparation of zirconium phosphate (ZrP)/Nafion1135 composite membrane and H+/VO2+ transfer property investigation[J].Journal of Membrane Science,2007(1/2):118-124. |
| [19] | 滕祥国,赵永涛,席靖宇,武增华,邱新平,陈立泉.全钒氧化还原液流电池用Nafion/有机硅复合膜[J].化学学报,2009(06):471-476. |
| [20] | Xi Jingyu;Wu Zenghua;Teng Xiangguo et al.Self-assembled polyeryelectrolyte multilayer modified Nafion membrane with suppressed vanadium ion crossover for vanadium redox flow batteries[J].Journal of Materials Chemistry,2008,18(11):1132-1238. |
| [21] | 邱景义,马骏,翟茂林.全钒液流电池离子交换膜合成方法综述[J].膜科学与技术,2011(06):101-105,110. |
| [22] | Luo QT;Zhang HM;Chen J;Qian P;Zhai YF .Modification of Nafion membrane using interfacial polymerization for vanadium redox flow battery applications[J].Journal of Membrane Science,2008(1/2):98-103. |
| [23] | Zeng jie;jiang Chunping;Wang Yaohui et al.Studies on polypyrole modified Nafion membrane for vanadium redox flow battery[J].Electrochem Common,2008,10(03):372-375. |
| [24] | Schwenzer B;Kim S;Vijayakumar M et al.Correlation of structural differences between Nafion/polyaniline and Nafion/polypyrrole composite membranes and observed transport properties[J].Journal of Membrane Science,2013,372(1-2):11-19. |
| [25] | Mai Zhensheng;Zhang Huamin;Lixianfeng et al.Nafion/polyinylidene fluoride blend membranes with improved ion selectivity for vanadium redox flow battery application[J].Journal of Power Sources,2011,196:5737-5741. |
| [26] | Wenping Wei;Huamin Zhang;Xianfeng Li;Zhensheng Mai;HongzhangZhang .Poly(tetrafluoroethylene) reinforced sulfonated poly(ether ether ketone) membranes for vanadium redox flow battery application[J].Journal of Power Sources,2012(Jun.15):421-425. |
| [27] | Jia Chuankun;Liu Jianguo;Yan Chuanwei .A multilayered membrane for vanadium redox flow battery[J].Journal of Power Sources,2012,203:190-194. |
| [28] | Wang Nanfang;Peng Sui;Wang Hongmei et al.A SPPEK/WO3 hybrid membrane fabricated via Hydrothermal method for vanadium redox flow battery[J].ELECTROCHEMISTRY COMMUNICATIONS,2012,17:30-33. |
| [29] | Chen Dongyang;Wang Shuanjin;Xiao Min et al.Synthesis and characterization of novel sulfonated poly (arylene thiether) ionomers for vanadium redox flow battery application[J].Energy Environ SCi,2010,3(05):622-628. |
| [30] | Sulfonated poly (fluorenyl ether ketone) membrane with embedded silica rich layer and enhanced proton selectivity for vanadium redox flow battery[J].Journal of Power Sources,2010(22):7701-7708. |
| [31] | 王保国.新能源领域的质子交换膜研究与应用进展[J].膜科学与技术,2010(01):1-8. |
| [32] | 吕正中,胡嵩麟,罗绚丽,武增华,陈立泉,邱新平.质子交换膜对钒氧化还原液流电池性能的影响[J].高等学校化学学报,2007(01):145-148. |
| [33] | Qiu Jingyi;Zhao Long;Zhai Maolin et al.Pre-irradiation of styrene and maleic anhydride onto PVDF membrane and subsequent sulfonation for application in vanadium redox batteries[J].Journal of Power Sources,2008,177(02):617-623. |
| [34] | 邱景义;王玉;翟茂林.全钒液流电池离子交换膜的辐射接枝制备及表征[A].,2009:116-123. |
| [35] | 桑商斌,黄可龙,石瑞成,王小波.PVA-ZrP复合膜作为全钒液流电池隔膜的研究[J].中南大学学报（自然科学版）,2005(06):1011-1016. |
| [36] | Xi Gao Jian,Chun Yan,Hua Min Zhang,Shou Hai Zhang,Cheng Liu,Ping Zhao.Synthesis and characterization of quaternized poly(phthalazinone ether sulfone ketone) for anion-exchange membrane[J].中国化学快报（英文版）,2007(10):1269-1272. |
| [37] | 徐敏;尚玉明;谢晓峰 等.全钒电池用多氟聚嗯二唑芳醚阴离子交换膜的制备[J].化学学报,2011,62(02):150-154. |
| [38] | Jingyi Qiu;Mengyuan Li;Jiangfeng Ni;Maolin Zhai;Jing Peng;Ling Xu;Henghui Zhou;Jiuqiang Li;Genshuan Wei .Preparation of ETFE-based anion exchange membrane to reduce permeability of vanadium ions in vanadium redox battery[J].Journal of Membrane Science,2007(1/2):174-180. |
| [39] | Qiu Jingyi;Zhang Junzhi;Chen Jinhua et al.Amphoteric ion exchange membrane synthesized by radiation-induced graft copolymerization of styrene and dimethyl amino ethyl methacrylate into PVDF film for vanadium redox flow battery applications[J].Journal of Membrane Science,2009,334(1-2):9-15. |
| [40] | Qiu Jingyi;Zhai Maolin;Chen Jinhua et al.Performance of vanadium redox flow battery with a novel amphoteric ion exchange membrane synthesized by twostep grafting method[J].Journal of Membrane Science,2009,342(1-2):215-220. |
| [41] | N.Hilal;H.Al-Zoulbi;N.A.Darwish .A comprehensive review of nanofiltration membranes:Treatment,pretreatment,modelling,and atomic force microscopy[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2004(3):281-308. |
| [42] | Hongzhang Zhang;Huamin Zhang;Xianfeng Li;Zhensheng Mai;Jianlu Zhang .Nanofiltration (NF) membranes: the next generation separators for all vanadium redox flow batteries (VRBs)?[J].Energy & environmental science: EES,2011(5):1676-1679. |
| [43] | Oriji G;Katayama Y;Miura T .Investigations on Ⅴ (Ⅳ)/Ⅴ(Ⅴ) and Ⅴ(Ⅱ)/Ⅴ(Ⅲ) redox reactions by various electrochemical methods[J].Journal of Power Sources,2005,139:321-324. |
| [44] | Tuckerman M;Laasonen K;Sprik M et al.A initio molecular dynamics simulation of the solvation and transport of H30+ and OH-ions in water[J].Journal of Physical Chemistry,1995,99:5749-5752. |
| [45] | Hongzhang Zhang;Huamin Zhang;Xianfeng Li;Zhensheng Mai;Wenping Wei .Silica modified nanofiltration membranes with improved selectivity for redox flow battery application[J].Energy & environmental science: EES,2012(4):6299-6303. |
| [46] | Wei Wenping;Zhang Huamin;Li Xianfeng et al.Hydrophobic asymmetric ultrafiltration PVDF membranes:an alternative separator for VFB with excellent stability[J].Physical Chemistry Chemical Physics,2013,15(06):1766-1771. |
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