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利用脂肪酸与多胺合成咪唑啉,对咪唑啉进行改性得到一种新型含硫磷的咪唑啉类缓蚀刘HGYT。通过高温高压动态测试和电化学方法研究了HGY-T在温度为80℃,CO2分压为1MPa高矿化度的模拟油川水中的缓蚀性能。结果表明,在高温高压二氧化碳介质中,50mg/L的缓蚀剂就有很好的缓蚀性能,腐蚀速率低于0.076mm/a,缓蚀率达到95%。该缓蚀剂为阳极型缓蚀剂.遵循Frumkin吸附等温式。

A new kind of modified imidazoline corrosion inhibitor containing sulfur and phosphor was synthesized using fatty acid and polyamine. The inhibition effect of modified imidazoline HGYT was investigated using autoclabe and electrochemical method in simulated well producing water saturated with 1 MPa COe at 80 (7. The resuhs showed that in the medium with high pressure and high temperature CO2, the corrosion rate of steel was less than 0. 076 mm/a with adding 50 mg/L inhibitor. The modified imidazoline is an anodic inhibitor and obeys the Frumkin adsorption isothermal equation.

参考文献

[1] 刘多容,孙勇,潘成松,黄贵存.CO2气液两相缓蚀剂SM-12B及其性能评价[J].腐蚀与防护,2011(04):281-284.
[2] 杜敏,王彬,张静,王宁.温度对新型咪唑啉抑制CO2腐蚀的影响[J].材料保护,2010(09):20-23,27.
[3] 陈国浩,陈波,赵景茂,魏振禄.改性聚酰胺对CO2环境中N80钢的缓蚀作用[J].腐蚀与防护,2010(06):444-446.
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