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通过丝网印刷技术,将碳纳米管(carbon nanotube,CNT)浆料直接转移到CrCuCr薄膜衬底电极、掺Sn的In_2O_3(indium tin oxides,ITO)透明导电薄膜衬底电极和Ag浆导电厚膜衬底电极上,高温烧结后得到CNT阴极,并对CNT阴极进行表面形貌和场发射性能的研究.结果表明,不同衬底电极对CNT阴极场发射性能的影响不一样,CrCuCr薄膜衬底电极CNT阴极、ITO透明导电薄膜衬底电极CNT阴极及Ag浆厚膜导电衬底电极CNT阴极场发射的开启电场分别为0.99、2.05和2.46V/μm;当电场为3.0V/μm时,它们的亮度分别为2472、1889、587cd/m~2.CrCuCr薄膜衬底电极CNT阴极的场发射性能最优,ITO透明导电薄膜衬底电极CNT阴极次之,Ag浆厚膜导电衬底电极CNT阴极最差,并根据金属-半导体理论模型分析了原因.

The effect of field emission properties of carbon nanotube (CNT) cathodes on CrCuCr thin-film, indium tin oxides (ITO) transparent-film and silver (Ag) paste thick-film were investigated, which prepared by screen-printing, sintered with high temperature. The morphologies of CNT cathodes on different electrode substrates were observed by scanning electron mircroscope (SEM), and the field emission properties were characterized in the same condition of 1. 33×10~(-5)Pa. The results showed that three kinds of CNT cathodes have different field emission properties. The field emission tests indicate that the turn on electric field of the CNT cathode on CrCuCr thin-film is 0. 99V/mm, the one on ITO thin-film's 2. 05V/mm, the one on Ag paste thick-film's 2. 46V/mm. When the electric field is 3. 0V/μm, the brightness luminosities of CrCuCr-cathode, ITOcathode and Ag paste-cathode were 2472, 1889, 587cd/m~2, respectively. It can be speculated that the field emission property of the CNT cathode on CrCuCr thin-film takes precedence over the others, and the one on Ag paste thick-film is lousiest.

参考文献

[1] Iijima S .[J].Nature,1991,354(6348):56-58.
[2] Deheer WA;Bacsa WS;Chatelain A;Gerfin T;Humphreybaker R;Forro L .ALIGNED CARBON NANOTUBE FILMS - PRODUCTION AND OPTICAL AND ELECTRONIC PROPERTIES[J].Science,1995(5212):845-847.
[3] 朱绍文,贾志杰.碳纳米管及其应用的研究现状[J].功能材料,2000(02):119-120.
[4] 徐冬梅,吴华强,王谦宜,王强,牛贝,胡宗铭.碳纳米管负载FeCoNi纳米复合材料的制备及磁性研究[J].功能材料,2007(11):1777-1779.
[5] 吴玉程,宋林云,刘晓璐,叶敏,解挺,张立德.碳纳米管负载纳米TiO2复合材料的制备及组织结构表征[J].功能材料,2008(03):497-498,502.
[6] H.J. Lee;Y.D. Lee;S.I. Moon .Enhanced surface morphologies of screen-printed carbon nanotube films by heat treatment and their field-emission properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(13):2625-2630.
[7] Hou ZY;Cai BC;Liu H;Xu D .Ar, O-2, CHF3, and SF6 plasma treatments of screen-printed carbon nanotube films for electrode applications[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(3):405-413.
[8] Jung Y J;Park J H;Jeon S Y et al.[J].Diamond and Related Materials,2006,15(11-12):1855-1858.
[9] Fennimore A M;Cheng L T;Roach D H .[J].Diamond and Related Materials,2008,17(12):2005-2009.
[10] Su X;Zhang L;Lei W.[J].Ultramicroscopy,2007(107):844-848.
[11] Li J T;Lei W;Zhang X et al.[J].Applied Surface Science,2003,220(1-4):96-104.
[12] Odintsov A A;Tokura Y .[J].Physical Review B:Condensed Matter,2000,284(2002):1752-1753.
[13] Electronic structure of the contact between carbon nanotube and metal electrodes[J].Applied physics letters,2003(15):3180-3182.
[14] Antonis N. Andriotis;Madhu Menon;George E. Froudakis .Various bonding configurations of transition-metal atoms on carbon nanotubes: Their effect on contact resistance[J].Applied physics letters,2000(26):3890-3892.
[15] Kowalsk E;Czerwosz E;Dluzewski P A et al.[J].Diamond and Related Materials,2004,13(4-8):1005-1011.
[16] 曾乐勇;王维彪;粱静秋 等.衬底氮化时间对玻璃衬底上低温沉积GaN薄膜结晶性的影响[J].功能材料与器件学报,2008,14(04):763-767.
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