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以甲酸溶解壳聚糖(CS)、三氯甲烷/乙醇混合溶剂溶解聚乳酸(PLA),两溶液混合后得均质纺丝液,通过静电纺丝制备出CS/PLA复合纳米纤维.采用扫描电镜(SEM)、傅立叶变换红外光谱(FT-IR)对纤维的形态与结构进行分析表征.结果表明,质量分数1.6%的CS甲酸溶液与质量分数15%的PLA三氯甲烷/乙醇混合溶液(三氯甲烷:乙醇=1:1,体积比)等体积混合,电压15 kV,极距15 cm下,可得到均匀的直径为(290±28) nm的CS/PLA复合纳米纤维,且CS和PLA分子间以氢键结合.

参考文献

[1] Paul D.Dalton;Dirk Grafahrend;Kristina Klinkhammer .Electrospinning of polymer melts:Phenomenological observations[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(23):6823-6833.
[2] Sill TJ;von-Recum HA .Electrospinning: applications in drug delivery and tissue engineering.[J].Biomaterials,2008(13):1989-2006.
[3] Artphop Neamnark;Ratana Rujiravanit;Pitt Supaphol .Electrospinning of hexanoyl chitosan[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2006(3):298-305.
[4] Touny, A.H.;Bhaduri, S.B. .A reactive electrospinning approach for nanoporous PLA/monetite nanocomposite fibers[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2010(8):1304-1312.
[5] Vieira AC;Vieira JC;Ferra JM;Magalhaes FD;Guedes RM;Marques AT .Mechanical study of PLA-PCL fibers during in vitro degradation.[J].Journal of the mechanical behavior of biomedical materials,2011(3):451-460.
[6] Jia Xu;Jinhui Zhang;Weiquan Gao;Hongwei Liang;Hongyan Wang;Junfeng Li .Preparation Of Chitosan/pla Blend Micro/nanofibers By Electrospinning[J].Materials Letters,2009(8):658-660.
[7] Bhardwaj, Nandana;Kundu, Subhas C. .Electrospinning: A fascinating fiber fabrication technique[J].Biotechnology Advances,2010(3):325-347.
[8] Deitzel JM.;Harris D.;Tan NCB.;Kleinmeyer J. .The effect of processing variables on the morphology of electrospun nanofibers and textiles[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(1):261-272.
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