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热轧过程中,不同的轧制工艺和卷取条件会获得不同的氧化铁皮结构。其中,FeO的晶粒是以三角锥型或金字塔型的方式生长,Fe3O4以柱状晶的形式生长,Fe2O3以金属须状方式生长。针对不同结构的氧化铁皮进行酸洗模拟试验,研究热轧带钢不同位置的氧化铁皮的酸洗行为,绘制了不同氧化铁皮结构的酸洗动力学曲线,分析由于供氧差异对氧化铁皮结构和酸洗行为造成的影响;并揭示了两种典型氧化铁皮结构的酸洗机制,以FeO为主的氧化铁皮结构其酸洗机制为“剥离”、化学溶解和相结合,以Fe3O4为主的氧化铁皮结构其酸洗机制以化学溶解为主。

Significant structural differences can be found in oxide scales formed on hot-rolled strip processed under different hot rolling conditions and at different locations in the coil. It was found that wustite crystal grew in the form of triangular pyramidal, and magnetite grew in the form of columnar crystal. Hematite developed in whiskers ways. The pickling simulation experiments on different scales were done to study the acid-pickling behaviors of the oxide scale at different positions in plate width and the pickling kinetics curve was draw, the effect of the differ- ence in oxygen supply in the width direction on the scale structure and acid-pickling behavior of hot-rolled strip were analyzed. There are two different pickling mechanisms of hot-rolled steel strip for the typical structure, one is the combination of "stripping", chemical dissolve and for FeO, another is chemical dissolve for Fe3O4.

参考文献

[1] Gleeson B;Hadavi S M M;Young D J .Isothermal Transfor- mation Behavior of Thermally-Grown WiaStite Meter[J].High Temperature,2000,17(02):311.
[2] 刘振宇,于洋,郭晓波,关菊,王国栋.板带热连轧中氧化铁皮的控制技术[J].轧钢,2009(01):5-9.
[3] CHEN R Y;Yuen W Y D .A Study of Scale Structure of Hot- Rolled Steel Strip by Simulated Coiling and Cooling[J].Oxi dation of Metals,2000,53(03):539.
[4] Klaus S;ZHOU S X.Contribution to Scale Growth During Hot Rolling of Steel[J].Metalworking,2003(09):538.
[5] Hudson R M .Nonacidic Desealing of Hot Band:Reduction of Hydrogen or Carbon[J].Metal Finishing,1985,83(11):73.
[6] Wever F;Engell H J .Electrochemische Untersuchungen Uber Den Einflub Des Walz and Gluhzunders Von Stahl Auf DieKorrosion Und Uber Den Beizvorgang[J].Arch Eisen,1956,7(07):475.
[7] Frisch B;Thiele W R;Prediger D .Die Wirkung Zunderfreier Oberflachenanteile Auf Nichtinhibierte Und lnhibierte Beiz- prozesse an Stahlen[J].Arch Eisen,1983,54(08):311.
[8] Goursat A G;Smeltzer W W .Kinetics and Morphological Develop- ment of the Oxide Scale on Iron at High Temperature in Oxygen at Low Pressure[J].Oxidation of Metals,1973,6(02):101.
[9] Aballah I;Elraghy S;Gleitzer C .Oxidation Kinetics of Fay- ality and Growth of Hematite Whiskers[J].Journal of Mate- rials Science,1978,13(01):1971.
[10] Markworth A J .On the Kinetics of Isothermal Oxidation[J].Metallurgical and Materials Transactions,1977,8(10):2014.
[11] CHEN R Y;Yuen W Y D.On the Pickling Mechanisms of Hot-Rolled Steel Strip[A].Orlando:[s.n.],2002:1077.
[12] CHEN R Y;Yuen W Y D.Improvement of Pickling Charac teristics of Hot-Rolled Strip Through Heat Treatment of the Oxide Scale[A].Or- lando:[s.n.],2002:1057.
[13] Frisch B;Thiele W R;Doenhardt W .Method and Applica- tion of a Quantitative Laboratory Simulation of Technical Pickling Processes[J].Stahl Und Eisen,1986,106(11):641.
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