欢迎登录材料期刊网

材料期刊网

高级检索

通过自由基胶束共聚法制备了PBAM系列非离子型疏水缔合共聚物,并对聚合反应进行了研究,结果表明,丙烯酰胺的水相聚合反应动力学仍然适用于胶束共聚合过程;在聚合过程中由于表面活性剂胶束的存在,疏水单体在反应初期的嵌入率很高,而后期主要以丙烯酰胺均聚物为主,导致严重的微观结构非均匀性,而这种非均匀性时共聚物的增粘性能有很大的影响.

参考文献

[1] Taylor K C;Nasr-El-Din H A .[J].Journal of Petroleum Science and Engineering,1998,19:265.
[2] Ma JT.;Cui P.;Zhao L.;Huang RH. .Synthesis and solution behavior of hydrophobic association water-soluble polymers containing arylalkyl group[J].European Polymer Journal,2002(8):1627-1633.
[3] Peer W J;In Glass J E.Polymers in Aqueous Media:Performance Through Association Ch 20 Advance in Chemistry 223[J].Washington D C:American Chemical Society,1989:381.
[4] Dawling K C;Thomas J K .[J].MACROMOLECULES,1990,23(04):1059.
[5] Branham K D;Middleton J C;McCormick C L .[J].Polymeric Preprints(American Chemical Society Division of Polymer Chemistry),1991,32(01):106.
[6] McCormick C L;Middleton J C;Grady C E .[J].POLYMER,1992,33(19):4184.
[7] Hill A;Candau F;Selb J .[J].Macromolecules,1993,26:4521.
[8] Candau F.;Selb J. .Hydrophobically-modified polyacrylamides prepared by micellar polymerization[J].Advances in Colloid and Interface Science,1999(2/3):149-172.
[9] Freid J P;Alexander A E .[J].Journal of Polymer Science Part A:Polymer Chemistry,1978,6:1833.
[10] 李干佐,郝京诚,杜贞伟,汪汉卿,夏瑞.丙烯酰胺在胶束和微乳液中聚合动力学研究[J].科学通报,1995(09):799-802.
[11] Biggs S;Selb J;Candau F.[J].LANGMUIR,1992(03):838.
[12] Candau F.;Selb J. .Hydrophobically-modified polyacrylamides prepared by micellar polymerization[J].Advances in Colloid and Interface Science,1999(2/3):149-172.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%