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研究了弹性体(POE)、滑石粉、偶联剂和填料处理方式对聚丙烯(PP)的力学性能、加工性能、结晶行为以及无机粒子在基体中分散形态的影响.结果表明,PP2(K7726)/POE(80/20)二元共混体系的综合性能较好;采用方式C(将两种偶联剂按1∶1的质量比,先加钛酸酯后加硅烷处理滑石粉)制得的PP2/POE/Talc(80/20/25)三元复合材料的力学性能比其它两种方式有显著提高.偏光显微镜(PLM)研究表明,方式C处理的滑石粉在体系中分散性最好;扫描电镜(SEM)显示,三元复合体系由PP2/POE耗能少的空洞化断裂方式向耗能多的剪切屈服方式转变;DSC表明,采用方式C处理的滑石粉对聚丙烯的成核作用减弱.

参考文献

[1] Leong Y W;Abu Bakar M B;Mohd Z AIshak;A Ariffin .[J].Polymer Degradation and Stability,2004,83:411-422.
[2] Zhang XF.;Xie F.;Pen ZL.;Zhang Y.;Zhang YX.;Zhou W. .Effect of nucleating agent on the structure and properties of polypropylene/poly(ethylene-octene) blends[J].European Polymer Journal,2002(1):1-6.
[3] Collar EP.;Laguna O.;Areso S.;Garcia-Martinez JM. .Succinyl fluorescein grafted atactic polypropylene as an interface modifier in polypropylene/talc composites: a thermal study under dynamic conditions[J].European Polymer Journal,2003(1):157-163.
[4] Li Z.;Guo SY.;Song WT.;Hou B. .Effect of interfacial interaction on morphology and mechanical properties of PP/POE/BaSO4 ternary composites[J].Journal of Materials Science,2003(8):1793-1802.
[5] Li Z.;Guo SY.;Song WT.;Yan Y. .Effect of the interfacial interaction on the phase structure and rheological behavior of polypropylene/ethylene-octene copolymer/BaSO4 ternary composites[J].Journal of Polymer Science, Part B. Polymer Physics,2002(17):1804-1812.
[6] Paul S.;Kale DD. .Rheological study of polypropylene copolymer/polyolefinic elastomer blends[J].Journal of Applied Polymer Science,2002(3):665-671.
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