对高Nb含量的316LN奥氏体不锈钢,在650、750和800℃时效处理不同时间.通过定量金相,SEM、XRD及TEM等分析技术,分析了析出相随时效时间和温度的变化关系.结果表明:时效初期,析出相沿晶界呈颗粒状、短棒状析出,随时效时间延长析出相沿晶界呈链状析出,析出量不断增多,并逐渐向晶内生长,最终以不连续的片状布满整个晶面.750℃为时效敏感温度,该时效温度下,析出相的量最多,孕育时间最短.整个时效阶段,时效优先析出相为Z-CrNbN相,且作为氮化物的主要存在形式,而不是常见的ε-Cr2N相.316LN不锈钢中,Nb元素的添加,一定程度上抑制了ε-Cr2N相和Z-Cr23C6相的析出,加速了σ-FeCrMo相的析出.
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