用原位氧化聚合法将聚苯胺分子链插入层状五氧化二钒的片层中,从而制得了一系列聚苯胺/五氧化二钒(PAn/V2O5)杂化纳米复合材料.采用WAXD、FT-IR、TGA及四探针电导率测量等手段对产物进行表征,结果表明,聚苯胺分子以单层形式在受限的纳米空间(五氧化二钒的片层中)生成,聚苯胺以伸展的单分子链存在,自由电子得到充分离域,PAn/V2O5杂化材料室温电导率在10-3S/cm～10-2S/cm之间.
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