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采用熔融接枝法制备两亲性改性剂聚丙烯接枝聚乙烯吡咯烷酮(PP-g-PVP),热致相分离法制备聚丙烯亲水微孔膜.利用元素分析仪测定了PP-g-PVP的接枝率,采用接触角测定仪、场发射扫描电子显微镜和旋转流变仪对聚丙烯亲水微孔膜进行了测试和研究.结果显示,两亲性改性剂PP-g-PVP的接枝率和接枝效率分别是16.44%和56.78%;制成的聚丙烯素水微孔膜亲水性有明显提高,由不润湿状态转为润湿状态,且在短时间内水滴可以较快地铺平;在降温过程中,液-液相分离到结晶的时间缩短,导致亲水膜的孔径减小,可以有效地阻隔污染物的通过.

参考文献

[1] Yun-Feng Yang;Ling-Shu Wan;Zhi-Kang Xu .Surface Engineering of Microporous Polypropylene Membrane for Antifouling: A Mini-Review[J].Journal of Adhesion Science and Technology: The International Journal of Theoredtical and Basic Aspects of Adhesion Science and Its Applications in All Areas of Technology,2011(1/3):245-260.
[2] Hengchong Shi;Dean Shi;Ligang Yin .Preparation of PP-g-PEG by using partial pre- irradiated polypropylene as initiator and its properties[J].Polymer bulletin,2010(9):929-940.
[3] Synthesis and enrichment of a macromolecular surface modifier PP-b-PVP for polypropylene[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2010(10):3240.
[4] 陈汉佳,祝亚非,张艺,许家瑞.添加型聚丙烯大分子表面改性剂PP-g-PEG的制备及其应用[J].高分子学报,2007(02):203-208.
[5] 周婧 .热致相分离法制备亲水性微孔膜及其改性研究[D].复旦大学,2009.
[6] 陈学民,唐玉霖,伏小勇.中空纤维膜生物反应器膜污染影响因素[J].净水技术,2011(01):33-38,66.
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