在概述染料敏化太阳能电池工作原理基础上,着重分析电池光阳极TiO<,2>薄膜的特性,并指出该薄膜在电池中所起的作用:负载染料、收集光生电子、分离电荷和传输光生电子;继而从表面修饰、离子掺杂、量子点敏化、制备复合薄膜、设计微观有序空间结构、设计核壳结构以及多手段共改性等方面对TiO<,2>薄膜改性手段进行综述,并详细分析改性手段优化染料敏化太阳能电池性能的原因;最后,提出应把优化光阳极TiO<,2>薄膜制备工艺及探讨薄膜接触面工作机理等作为今后的研究重点.
参考文献
| [1] | O'Regan B;Graztel M .A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J].Nature,1991,353(24):737. |
| [2] | Nazeeruddin M K;Kay A;Rodicio I et al.Conversion of light to electricity by cis-X2bis (2,2'-bipyridyl-4,4'-dicarboxylate) ruthenium(Ⅱ) charge-transfer sensitizers (X = Cl-,Br-,I-,CN-,and SCN-) on nanocrystalline titanium dioxide electrodes[J].Journal of the American Chemical Society,1993,115(14):6382. |
| [3] | 高建华,钱伟君,吴伟,曾毅.染料敏化太阳能电池TiO2薄膜的制备方法[J].理化检验-物理分册,2008(08):431-436,442. |
| [4] | Roy P;Kim D;Paramasivam I et al.Improved efficiency of Tick nanotubes in dye sensitized solar cells by decoration with Tick nanoparticles[J].Electrochemistry Communications,2009,11(05):1001. |
| [5] | Patcharee Charoensirithavorn;Yuhei Ogomi;Takashi Sagawa .Improvement of Dye-Sensitized Solar Cell Through TiCl_4-Treated TiO_2 Nanotube Arrays[J].Journal of the Electrochemical Society,2010(3):B354-B356. |
| [6] | 刘尧,王维波,肖绪瑞,张东社.纳晶多孔TiO2薄膜电极的化学处理[J].科学通报,2000(09):929-932. |
| [7] | 李文欣,胡林华,戴松元.染料敏化太阳电池研究进展[J].中国材料进展,2009(07):20-25. |
| [8] | Wang Z S;Li F Y;Huang C H .Photocurrent enhancement of hemicyanine dyes containing RSO《,3》-group through treating TiO2 films with hydrochloric acid[J].Journal of Physical Chemistry B,2001,105(38):9210. |
| [9] | P. Balraju;Manish Kumar;M.S. Roy .Dye sensitized solar cells (DSSCs) based on modified iron phthalocyanine nanostructured TiO_2 electrode and PEDOT:PSS counter electrode[J].Synthetic Metals,2009(13):1325-1331. |
| [10] | Hao S C;Wu J H;FanL Q et al.The influence of acid treatment of TiO2 porous film electrode on photoelectric perforraance of dye-sensitized solar cell[J].Journal of Solar Energy Engineering,2004,76(06):745. |
| [11] | Murayama M;Mori T .Evaluation of treatment effects for high-performance dye-sensitized solar cells using equivalent circuit analysis[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1/2):123-126. |
| [12] | Sanjeev Sharma;Oomman K. Varghese;Gopal K. Mor .Ethanol vapor processing of titania nanotube array films: enhanced crystallization and photoelectrochemical performance[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(23):3895-3898. |
| [13] | Park K H;Jin E M;Gu H B et al.Effects of HNOO《,3》 treatment of Tick nanoparticles on the photovohaic properties of dye-sensitized solar cells[J].Materials Letters,2009,63(26):2208. |
| [14] | 于涛 .TiO2基可见光响应纳米光催化剂制备、表征分析及性能研究[D].天津:天津大学,2010. |
| [15] | Tao Yu;Xin Tan;Lin Zhao .Characterization, activity and kinetics of a visible light driven photocatalyst: Cerium and nitrogen co-doped TiO2 nanoparticles[J].Chemical engineering journal,2010(1):86-92. |
| [16] | 黄娟茹,李明伟,崔忠.TiO2光催化剂掺杂改性的研究进展[J].工业催化,2007(01):1-7. |
| [17] | 李明伟,崔忠,黄娟茹,韩丽,魏艳艳.低温制备二氧化钛光催化剂薄膜的研究进展[J].现代化工,2007(03):26-29,31. |
| [18] | Cham Kim;Ki-Soo Kim;Ho Young Kim .Modification of a TiO_2 photoanode by using Cr-doped TiO_2 with an influence on the photovoltaic efficiency of a dye-sensitized solar cell[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2008(47):5809-5814. |
| [19] | Hugo Alarcon;Maria Hedlund;Erik M.J.Johansson .Modification of Nanostructured TiO2 Electrodes by Electrochemical Al~(3+)Insertion:Effects on Dye-Sensitized Solar Cell Performance[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(35):13267-13274. |
| [20] | 李树全,林建明,吴季怀,张秀坤,李彪,徐波.Ho3+上转换发光在染料敏化太阳能电池中的应用[J].功能材料,2009(01):82-85. |
| [21] | 杨术明,李富友,黄春辉.染料敏化稀土离子修饰二氧化钛纳米晶电极的光电化学性质[J].中国科学B辑,2003(01):59-65. |
| [22] | Reyes-Gil KR;Reyes-Garcia EA;Raftery D .Photoelectrochemical analysis of anion-doped TiO2 colloidal and powder thin-film electrodes[J].Journal of the Electrochemical Society,2006(7):A1296-A1301. |
| [23] | Ma TL;Akiyama M;Abe E;Imai I .High-efficiency dye-sensitized solar cell based on a nitrogen-doped nanostructured titania electrode[J].Nano letters,2005(12):2543-2547. |
| [24] | Kang SH;Kim JY;Kim YK;Sung YE .Effects of the incorporation of carbon powder into nanostructured TiO2 film for dye-sensitized solar cell[J].Journal of Photochemistry and Photobiology, A. Chemistry,2007(2/3):234-241. |
| [25] | Kang S H;KimJ Y;Sung Y E .Role of surface state on the electron flow in modified TiO2 film incorporating carbon powder for a dye-sensitized solar cell[J].Electrochimica Acta,2007,52(16):5242. |
| [26] | Huajun Tian;Linhua Hu;Changneng Zhang .Retarded Charge Recombination in Dye-Sensitized Nitrogen-Doped TiO2 Solar Cells[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(3):1627-1632. |
| [27] | Sykora M;Petruska M A;Alstrurn-Acevedo J et al.Photoinduced charge transfer between CdSe nanocrystal quanturn dots and Ru-polypyridine complexes[J].Journal of the American Chemical Society,2006,128:9984. |
| [28] | Yuh-Lang Lee;Yi-Siou Lo .Highly Efficient Quantum-dot-sensitized Solar Cell Based On Co-sensitization Of Cds/cdse[J].Advanced functional materials,2009(4):604-609. |
| [29] | Lee H;Leventis H C;Moon S J et al.PbS and US quantum dot-sensitized solid-state solar ceils:Old concepts,new results[J].Advanced Functional Materials,2009,19(17):2735. |
| [30] | Lee, HJ;Chen, P;Moon, SJ;Sauvage, F;Sivula, K;Bessho, T;Gamelin, DR;Comte, P;Zakeeruddin, SM;Il Seok, S;Gratzel, M;Nazeeruddin, MK .Regenerative PbS and CdS Quantum Dot Sensitized Solar Cells with a Cobalt Complex as Hole Mediator[J].Langmuir: The ACS Journal of Surfaces and Colloids,2009(13):7602-7608. |
| [31] | Zaban A.;Gregg BA.;Nozik AJ.;Micic OI. .Photosensitization of nanoporous TiO2 electrodes with InP quantum dots[J].Langmuir: The ACS Journal of Surfaces and Colloids,1998(12):3153-3156. |
| [32] | Xian-Feng Gao;Hong-Bo Li;Wen-Tao Sun .CdTe Quantum Dots-Sensitized TiO2 Nanotube Array Photoelectrodes[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(18):7531-7535. |
| [33] | Chou C S;Yang R Y;Yeh C K et al.Preparation of TiO2/ nano-metal composite particles and their applications in dyesensitized solar cells[J].Journal of Power and Energy,2009,194(1-2):95. |
| [34] | Sawatsuk T;Chindaduang A;Sae-Kung C et al.Dye-sensitized solar cells based on TiO2-MWCNTs composite electrodes:Performance improvement and their mechanisms[J].Diamond and Related Materials,2009,18(2-3):524. |
| [35] | A. Kitiyanan;S. Sakulkhaemaruethai;Y. Suzuki .Structural and photovoltaic properties of binary TiO_2-ZrO_2 oxides system prepared by sol-gel method[J].Composites science and technology,2006(10):1259-1265. |
| [36] | The-Vinh Nguyen;Hyun-Cheol Lee;M. Alam Khan;O-Bong Yang .Electrodeposition of TiO_2/SiO_2 nanocomposite for dye-sensitized solar cell[J].Solar Energy,2007(4):529-534. |
| [37] | 王育乔,孙岳明,代云茜,宋铂.二氧化钛纳米管复合薄膜电极制备及其在染料敏化太阳能电池中的应用[J].东南大学学报（自然科学版）,2008(01):162-165. |
| [38] | 庞山,谢腾峰,张宇,魏霄,杜祖亮,王德军.TiO2/ZnO薄膜电极中光生电子的传输及其在太阳电池中的应用[J].高等学校化学学报,2007(11):2187-2189. |
| [39] | Gong D;Grimes C A;Varghese O K et al.Titanium oxide nanotube arrays prepared by anodic oxidation[J].Journal of Materials Research,2001,16(12):3331. |
| [40] | Shankar K;Mor G K;Prakasam H E et al.Highly-ordered TiO2 nanotube arrays up to 220μm in length:Use in water photoelectrolysis and dye-sensitized solar cells[J].Nanotechnology,2007,18(06):11. |
| [41] | Nageh K. Allam;Karthik Shankar;Craig A. Grimes .A General Method for the Anodic Formation of Crystalline Metal Oxide Nanotube Arrays without the Use of Thermal Annealing[J].Advanced Materials,2008(20):3942-3946. |
| [42] | Craig A. Grimes .Synthesis and application of highly ordered arrays of TiO2 nanotubes[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2007(15):1451-1457. |
| [43] | Ong KG;Varghese OK;Mor GK;Shankar K;Grimes CA .Application of finite-difference time domain to dye-sensitized solar cells: The effect of nanotube-array negative electrode dimensions on light absorption[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2007(4):250-257. |
| [44] | Shankar K;Bandara J;Paulose M;Wietasch H;Varghese OK;Mor GK;LaTempa TJ;Thelakkat M;Grimes CA .Highly efficient solar cells using TiO2 nanotube arrays sensitized with a donor-antenna dye[J].Nano letters,2008(6):1654-1659. |
| [45] | Karthik Shankar;James I. Basham;Nageh K. Allam .Recent Advances in the Use of TiO2 Nanotube and Nanowire Arrays for Oxidative Photoelectrochemistry[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(16):6327-6359. |
| [46] | Varghese, OK;Paulose, M;Grimes, CA .Long vertically aligned titania nanotubes on transparent conducting oxide for highly efficient solar cells[J].Nature nanotechnology,2009(9):592-597. |
| [47] | Feng XJ;Shankar K;Varghese OK;Paulose M;Latempa TJ;Grimes CA .Vertically Aligned Single Crystal TiO2 Nanowire Arrays Grown Directly on Transparent Conducting Oxide Coated Glass: Synthesis Details and Applications[J].Nano letters,2008(11):3781-3786. |
| [48] | Motonari Adachi;Yusuke Murata;Issei Okada .Formation of Titania Nanotubes and Applications for Dye-Sensitized Solar Cells[J].Journal of the Electrochemical Society,2003(8):G488-G493. |
| [49] | Motonari Adachi;Yusuke Murata;Jinting Jiu;Jun Takao .Highly Efficient Dye-Sensitized Solar Cells with a Titania Thin-Film Electrode Composed of a Network Structure of Single-Crystal-like TiO_2 Nanowires Made by the "Oriented Attachment" Mechanism[J].Journal of the American Chemical Society,2004(45):14943-14949. |
| [50] | Jiu J T;Isoda S;Wang F M et al.Dye-sensitized solar cells based on a single-crystalline TiO2 nanorod film[J].Journal of Physical Chemistry B,2006,110(05):2087. |
| [51] | Lei Yang;Yuan Lin;Jianguang Jia;Xurui Xiao;Xueping Li;Xiaowen Zhou .Light harvesting enhancement for dye-sensitized solar cells by novel anode containing cauliflower-like TiO_2 spheres[J].Journal of Power Sources,2008(1):370-376. |
| [52] | Wenli Wang;Hong Lin;Jianbao Li .Formation of Titania Nanoarrays by Hydrothermal Reaction and Their Application in Photovoltaic Cells[J].Journal of the American Ceramic Society,2008(2):628-631. |
| [53] | Soon Hyung Kang;Moon-Sung Kang;Hyun-Sik Kim;Jae-Yup Kim;Young-Hoon Chung;William H. Smyrl;Yung-Eun Sung .Columnar Rutile Tio_2 Based Dye-sensitized Solar Cells By Radio-frequency Magnetron Sputtering[J].Journal of Power Sources,2008(1):331-335. |
| [54] | Kang S H;Kim H S;KimJ Y et al.An investigation on electron behavior employing vertically-aligned TiO2 nanotube electrodes for dye-sensitized solar cells[J].Nanotechnology,2009,20(35):6. |
| [55] | Soon Hyung Kang;Ju-Wan Lim;Hyun Sik Kim .Photo and Electrochemical Characteristics Dependent on the Phase Ratio of Nanocolumnar Structured TiO2 Films by RF Magnetron Sputtering Technique[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(13):2777-2788. |
| [56] | Fan X;Chu ZZ;Wang FZ;Zhang C;Chen L;Tang YW;Zou DC .Wire-shaped flexible dye-sensitized solar cells[J].Advanced Materials,2008(3):592-595. |
| [57] | Peter Chen;Jeremie Brillet;Hari Bala .Solid-state dye-sensitized solar cells using TiO2 nanotube arrays on FTO glass[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(30):5325-5328. |
| [58] | Norma R.de Tacconi;Wilaiwan Chanmanee;Krishnan Rajeshwar .Photoelectrochemical Behavior of Polychelate Porphyrin Chromophores and Titanium Dioxide Nanotube Arrays for Dye-Sensitized Solar Cells[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(7):2996-3006. |
| [59] | Xueping Gao;Huaiyong Zhu;Guiling Pan;Shihai Ye;Ying Lan;Feng Wu .Preparation and Electrochemical Characterization of Anatase Nanorods for Lithium-Inserting Electrode material[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2004(9):2868-2872. |
| [60] | Kim SS.;Yum JH.;Sung YE. .Improved performance of a dye-sensitized solar cell using a TiO2/ZnO/Eosin Y electrode[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(4):495-505. |
| [61] | Zhang XT;Liu HW;Taguchi T;Meng QB;Sato O;Fujishima A .Slow interfacial charge recombination in solid-state dye-sensitized solar cell using Al2O3-coated nanoporous TiO2 films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2004(2):197-203. |
| [62] | Wu S;Han H W;Tai Q D et al.Enhancement in dye-sensitized solar cells based on MgO-coated TiO2 electrodcs by reactive DC magnetron sputtering[J].Nanotechnology,2008,19(21):6. |
| [63] | Sujuan Wu;Hongwei Han;Qidong Tai;Jing Zhang;Bo Lei Chen;Sheng Xu;Conghua Zhou;Ying Yang;Hao Hu;Xing-Zhong Zhao .Improvement in dye-sensitized solar cells with a ZnO-coated TiO_(2) electrode by rf magnetron sputtering[J].Applied physics letters,2008(12):122106-1-122106-3-0. |
| [64] | Sujuan Wu;Hongwei Han;Qidong Tai;Jing Zhang;Sheng Xu;Conghua Zhou;Ying Yang;Hao Hu;BoLei Chen;Xing-zhong Zhao .Improvement in dye-sensitized solar cells employing TiO_2 electrodes coated with Al_2O_3 by reactive direct current magnetron sputtering[J].Journal of Power Sources,2008(1):119-123. |
| [65] | 周卫,付宏刚,潘凯,田春贵,曲阳,孙家锺.电泳沉积法制备介孔TiO2/单壁碳纳米管薄膜[J].高等学校化学学报,2009(10):2036-2039. |
| [66] | Menzies D B;Dai Q;Bourgeois L et al.Modification of mesoporous TiO2 electrodes by surface treatment with titanium(Ⅱ),indium(Ⅲ) and zirconium(Ⅳ) oxide precursors:Preparation,characterization and photovoltaic performance in dye-sensitized nanocrystalline solar cells[J].Nanotechnology,2007,18(12):1. |
| [67] | Diamant Y;Chen S G;Melamed O et al.Core-shell nanoporous electrode for dye sensitized solar cells:The effect of the SrTiO《,3》 shell on the electronic properties of the TiO2 core[J].Journal of Physical Chemistry B: Materials, Surfaces, Interfaces & Biophysical,2003,107(09):1977. |
| [68] | Liu Z Y;Pan K;Liu M et al.Al2O《,3》-coated SnO2/TiO2 composite electrode for the dye-sensitized solar cell[J].Electrochimica Acta,2005,50(13):2583. |
| [69] | Shuyun Kuang;Lixia Yang;Shenlian Luo;Qingyun Cai .Fabrication, characterization and photoelectrochemical properties of Fe_2O_3 modified TiO_2 nanotube arrays[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(16):7385-7388. |
| [70] | Soon Hyung Kang;Jae-Yup Kim;Yukyeong Kim .Surface Modification of Stretched TiO2 Nanotubes for Solid-State Dye-Sensitized Solar Cells[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(26):9614-9623. |
| [71] | Jason A.Seabold;Karthik Shankar;Rudeger H.T.Wilke .Photoelectrochemical Properties of Heterojunction CdTe/TiO2 Electrodes Constructed Using Highly Ordered TiO2 Nanotube Arrays[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(16):5266-5273. |
| [72] | Gregg B A;Chen S G;Ferrere S .Enhanced dye-sensitized photoeonversion efficiency via reversible production of UVinduced surface states in nanoporous TiO2[J].Journal of Physical Chemistry B,2003,107(13):3019. |
| [73] | Lewis LN;Spivack JL;Gasaway S;Williams ED;Gui JY;Manivannan V;Siclovan OP .A novel UV-mediated low-temperature sintering of TiO2 for dye-sensitized solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(7/8):1041-1051. |
| [74] | Hyunbong Choi;Sanghoon Kim;Sang Ook Kang .Stepwise Cosensitization of Nanocrystalline TiO2 Films Utilizing Al2O3 Layers in Dye-Sensitized Solar Cells[J].Angewandte Chemie,2008(43):8259-8263. |
| [75] | Masaya Chigane;Mitsuru Watanabe;Masanobu Izaki .Preparation of Hollow Titanium Dioxide Shell Thin Films by Electrophoresis and Electrolysis for Dye-Sensitized Solar Cells[J].Electrochemical and solid-state letters,2009(5):E5-E8. |
| [76] | Albu SP;Ghicov A;Macak JM;Hahn R;Schmuki P .Self-organized, free-standing TiO2 nanotube membrane for flow-through photocatalytic applications[J].Nano letters,2007(5):1286-1289. |
| [77] | Kant K;Losic D .A simple approach for synthesis of TiO2 nanotubes with through-hole morphology[J].Phys Status Solidi R,2009,3(05):139. |
| [78] | Wang J;Lin ZQ .Freestanding TiO2 nanotube arrays with ultrahigh aspect ratio via electrochemical anodization[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(4):1257-1261. |
| [79] | Qingwei Chen;Dongsheng Xu Beijing .Large-Scale, Noncurling, and Free-Standing Crystallized TiO2 Nanotube Arrays for Dye-Sensitized Solar Cells[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(15):6310-6314. |
| [80] | Chin-Jung Lin;Wen-Yueh Yu;Shu-Hua Chien .Transparent electrodes of ordered opened-end TiO2-nanotube arrays for highly efficient dye-sensitized solar cells[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(6):1073-1077. |
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