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  4. 烯烃裂解中分子筛催化剂的稳定性研究进展

催化学报 , 2008, 29(9): 866-872.

烯烃裂解中分子筛催化剂的稳定性研究进展

薛念华 1, , 郭学锋 2, , 丁维平 3, , 陈懿 4,

1.南京大学化学化工学院介观化学教育部重点实验室,江苏南京,210093

2.南京大学化学化工学院介观化学教育部重点实验室,江苏南京,210093

3.南京大学化学化工学院介观化学教育部重点实验室,江苏南京,210093

4.南京大学化学化工学院介观化学教育部重点实验室,江苏南京,210093

基金项目:   国家重点基础研究发展计划(973计划)(2003CB615804)  

关键词： 烯烃 , 催化裂解 , 丙烯 , 分子筛 , 水热稳定性 , 积炭

Advances in Research of the Stability of Molecular Sieve Catalysts for Olefin Cracking

低碳烯烃催化裂解增产丙烯是一项新技术,高水热稳定催化剂的研究和开发是关键技术之一,硅酸铝分子筛催化剂因具有相对较好的稳定性而得到了广泛研究. 本文总结了HY, HZSM-5和 MCM-22等微孔、介孔以及具有微-介孔复合结构的新型分子筛在烯烃催化裂解反应中的稳定性,特别是水热稳定性方面的研究进展,归纳了提高酸性分子筛催化剂水热稳定性的方法,比较了不同方法制得分子筛的催化裂解性能,对高稳定性催化剂在实际应用中的问题和前景进行了探讨,为研发新一代低碳烯烃裂解催化剂提供参考.

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