欢迎登录材料期刊网

材料期刊网

高级检索

在不同温度下对Nd0.75Mg0.25(Ni0.8Co0.2)3.8储氢合金进行磁场热处理,分别对合金的电化学性能、磁性能、合金的相组成及点阵参数进行测试和计算.结果表明:合金在磁场热处理前后的相组成没有发生明显变化,主相均为Ce2Ni7型(Nd,Mg)2(Ni,Co)7相和CaCu5型NdNi5相.磁场热处理使Ce2Ni7型磁性相的易磁化轴沿c轴取向,且晶格参数c增大,氢质子在四面体间隙中迁移的势能减小,合金的倍率性能大幅提高.温度越高,磁场热处理对合金的倍率性能改善越明显.

参考文献

[1] Zylstra H;Westendorp F F .[J].Solid State Communications,1969,7:857.
[2] Schlapbach L .[J].Journal of Physics F: Metal Physics,1980,10:2477.
[3] Fujino M;Yamamoto O;Yamaguchi M .[J].Journal of Alloys and Compounds,195,231:631.
[4] Fahidy T Z .[J].Journal of Applied Electrochemistry,1983,13:553.
[5] Aaboubi O;Chopart J P;Douglade J .[J].Journal of the Electrochemical Society,1990,137:1796.
[6] Watanabe K;Yamada Y;Sakuraba J et al.[J].Japanese Journal of Applied Physics,1993,32:LA88.
[7] Watanabe K;Awaji S .[J].Journal of Low Temperature Physics,2003,133:17.
[8] 张羊换,李保卫,蔡颖,董小平,任江远,王新林.快淬La-Mg-Ni系贮氢合金的电化学性能及微观结构[J].稀有金属材料与工程,2007(01):108-112.
[9] Liu Y F;Pan H G et al.[J].Journal of Alloys and Compounds,2004,365:246.
[10] Liao B;Lei Y Q;Chen L X et al.[J].Journal of Power Sources,2004,129:358.
[11] Zhang Faliang;Luo Yongchun et al.[J].Journal of Power Sources,2005,150:247.
[12] 张羊换,李保卫,任慧平,吴忠旺,董小平,王新林.快淬对La0.7Mg0.3Co0.45Ni2.55-xCux (x=0-0.4)电极合金微观结构及电化学性能的影响[J].稀有金属材料与工程,2008(06):941-946.
[13] 潘崇超;于荣海.[A].Richmond:World Scientific Publishing Co,2007:11.
[14] Wang C S;Klein B;Krakauer M .[J].Physical Review Letters,1985,54:1852.
[15] Szabo Z;Ivanyi A .[J].Journal of Magnetism and Magnetic Materials,2000,215:33.
[16] Fuzi J .[J].Journal of Magnetism and Magnetic Materials,2000,215:597.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%