季铵盐类农药属于强碱性极性有机阳离子化合物,易残留在环境中.传统的萃取方式难以对复杂基质中的痕量残留净化富集,其前处理方法一直是检测中的难点.近年来随着固相萃取材料不断更新与发展,固相萃取法已取代液-液萃取法成为季铵盐残留检测中主要应用的前处理方法.全面地描述了各类基质中季铵盐残留检测的前处理方法,重点分析与论述了目前常用的固相萃取材料的性质及优缺点,对其在前处理分析方法中涉及的重要方面做了较全面的分析与论述.
参考文献
| [1] | Pieó Y;Font G;Moltó J C et al.Solid-phase extraction of quaternary ammonium herbicides[J].Journal of Chromatography A,2000,885(1-2):251. |
| [2] | Ibá(n)ez M;Picó Y;Ma(n)es J .Improving the solid-phase extraction of "quat" pesticides from water samples removal of interferences[J].Journal of Chromatography A,1998,823(1-2):137. |
| [3] | Gill R;Qua S C;Moffat A C .High-performance liquid chromatography of paraquat and diquat in urine with rapid sample preparation involving ion-pair extraction on disposable cartridges of octadecyl-silica[J].Journal of Chromatography A,1983,255(01):483. |
| [4] | 王瑞花,苏少明,秦光明,李绍鹏,柴育芳,刘清.离子对SPE-HPLC法检测生物检材中的百草枯[J].法医学杂志,2005(02):121-123. |
| [5] | 刘菲,勉丽娜,张婧,康维钧.高效液相色谱法测定植物中的百草枯[J].中国卫生检验杂志,2009(06):1248-1249. |
| [6] | 成美容,王园朝,肖亮.毛细管电泳-间接电化学发光法对茶叶中百草枯农药残留的检测[J].分析测试学报,2009(12):1444-1447,1451. |
| [7] | Castro R;Moyano E;Galceran M T .Determination of quaternary ammonium pesticides by liquid chromatography-electrospray tandem mass spectrometry[J].Journal of Chromatography A,2001,914(1-2):111. |
| [8] | 张婷,谭家镒,齐宝坤,朱昱,姜兆林.气相色谱-串联质谱法分析尿和血中除草剂百草枯[J].中国法医学杂志,2009(03):161-163. |
| [9] | Whitehead, R.D.;Montesano, M.A.;Jayatilaka, N.K.;Buckley, B.;Winnik, B.;Needham, L.L.;Barr, D.B. .Method for measurement of the quaternary amine compounds paraquat and diquat in human urine using high-performance liquid chromatography-tandem mass spectrometry[J].Journal of chromatography, B. Analytical technologies in the biomedical and life sciences,2010(27):2548-2553. |
| [10] | Yong M;Jenklns K .河水中的百草枯和敌草快的SPE和LC-MS分析方法[J].环境化学,2004,23(06):722. |
| [11] | 李红梅,孙守威,史谢飞.高效安全的敌草快和百草枯液相色谱分离分析技术[J].分析化学,2007(10):1499-1502. |
| [12] | Nú(n)ez O;Moyano E;Galceran M T .Solid-phase extraction and sample stacking-capillary electrophoresis for the determination of quaternary ammonium herbicides in drinking water[J].Journal of Chromatography A,2002,946(1-2):275. |
| [13] | 赵永信,宋国良,张晶,徐小民,冯靓,吴平谷.气相色谱/质谱法测定粮食中矮壮素残留[J].中国卫生检验杂志,2008(06):1064-1066. |
| [14] | Zhou Q X;Mao J L;Xiao J P et al.Determination of paraquat and diquat preconcentrated with N doped TiO2 nanotubes solid plhase extraction cartridge prior to capillary electrophoresis[J].Analytical Methods,2010,2:1063. |
| [15] | X. Esparza;E. Moyano;M.T. Galceran .Analysis of chlormequat and mepiquat by hydrophilic interaction chromatography coupled to tandem mass spectrometry in food samples[J].Journal of chromatography, A: Including electrophoresis and other separation methods,2009(20):4402-4406. |
| [16] | Vidal JLM;Vega AB;Lopez FJS;Frenich AG .Application of internal quality control to the analysis of quaternary ammonium compounds in surface and groundwater from Andalusia (Spain) by liquid chromatography with mass spectrometry[J].Journal of chromatography, A: Including electrophoresis and other separation methods,2004(2):179-184. |
| [17] | 陈小华;汪群杰.固相萃取技术与应用[M].北京:科学出版社,2010:136. |
| [18] | Zougagh M;Bouabdallah M;Salghi R;Hormatallah A;Rios A .Supercritical fluid extraction as an on-line clean-up technique for rapid amperometric screening and alternative liquid chromatography for confirmation of paraquat and diquat in olive oil samples[J].Journal of chromatography, A: Including electrophoresis and other separation methods,2008(1):56-61. |
| [19] | 邱葵,吴华,张征,徐佳佳,杨梅,孔繁翠,王鹤尧.LC-MS/MS测定患者全血中百草枯的浓度[J].中国药学杂志,2009(16):1259-1261. |
| [20] | Zou, Y.;Shi, Y.;Bai, Y.;Tang, J.;Chen, Y.;Wang, L. .An improved approach for extraction and high-performance liquid chromatography analysis of paraquat in human plasma[J].Journal of chromatography, B. Analytical technologies in the biomedical and life sciences,2011(20):1809-1812. |
| [21] | 赵森,张云峰,王炯,于忠山.甲哌啶在大鼠体内的分布研究[J].中国药科大学学报,2013(02):147-150. |
| [22] | 陈璐,邹静,肖洪涛,何林,童荣生.高效液相色谱法测定人血清中百草枯浓度[J].中国医院药学杂志,2010(24):2091-2094. |
| [23] | Fuke C;Arao T;Morinaga Y et al.Analysis of paraquat,diquat and two diquat metabolites in biological materials by high-performance liquid chromatography[J].Legal Medicine,2002,4(03):156. |
| [24] | Kuo T L .Determination of paraquat in tissue using ion-pair chromatography in conjunction with spectrophotometry[J].Forensic science international,1987,33(03):177. |
| [25] | Nagata T et al.Simultaneous determination of paraquat and diquat in human tissues by high-performance liquid chromatography[J].Journal of Chromatography B,1993,617(01):119. |
| [26] | 张曦,金芬,钱永忠,于志勇,王静.高效液相色谱-串联质谱法测定樱桃番茄中四种季铵类农药[J].食品工业科技,2011(06):394-397. |
| [27] | Kolberg, D.I.S.;MacK, D.;Anastassiades, M.;Hetmanski, M.T.;Fussell, R.J.;Meijer, T.;Mol, H.G.J. .Development and independent laboratory validation of a simple method for the determination of paraquat and diquat in potato, cereals and pulses[J].Analytical and bioanalytical chemistry,2012(8):2465-2474. |
| [28] | Li W X;Chen M;Chen W T et al.Determination of mepiquat chloride in cotton crops and soil and its dissipation rates[J].Ecotoxicology and Environmental Safety,2012,85:137. |
| [29] | Marchese, S;Perret, D;Bafile, E;Gentili, A;Caretti, F;Berardino, M .Pressurized Liquid Extraction Coupled with LC-ESI-MS-MS for the Determination of Herbicides Chlormequat and Mepiquat in Flours[J].Chromatographia,2009(5/6):761-767. |
| [30] | Pateiro-Moure, M;Martinez-Carballo, E;Arias-Estevez, M;Simal-Gandara, J.Determination of quaternary ammonium herbicides in soils - Comparison of digestion, shaking and microwave-assisted extractions[J].Journal of chromatography, A: Including electrophoresis and other separation methods,2008:110-116. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%