橄榄石结构的LiFePO4工作电压3.4V,理论容量170mAh/g,充放电结构稳定,循环性能好,成本低,安全无毒,成为当前研究的热点.本文在介绍该材料的结构与性能的关系、充放电机理基础上,综述了近年来对该材料的研究进展,并提出了进一步发展的方向.
参考文献
[1] | Padhi AK.;Goodenough JB.;Nanjundaswamy KS. .PHOSPHO-OLIVINES AS POSITIVE-ELECTRODE MATERIALS FOR RECHARGEABLE LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1997(4):1188-1194. |
[2] | Andersson A S;Thomas J O .[J].Journal of Power Sources,2001,97-98:5498-502. |
[3] | Padhi AK.;Masquelier C.;Okada S.;Goodenough JB.;Nanjundaswamy KS. .EFFECT OF STRUCTURE ON THE FE3+/FE2+ REDOX COUPLE IN IRON PHOSPHATES[J].Journal of the Electrochemical Society,1997(5):1609-1613. |
[4] | Andersson AS.;Haggstrom L.;Thomas JO.;Kalska B. .Lithium extraction/insertion in LiFePO4: an X-ray diffraction and Mossbauer spectroscopy study[J].Solid state ionics,2000(1/2):41-52. |
[5] | Yamada A;Chung S C;Hinokuma K .[J].Journal of the Electrochemical Society,2001,148(03):A224-A229. |
[6] | Takahashi M.;Tobishima S.;Takei K.;Sakurai Y. .Reaction behavior of LiFePO4 as a cathode material for rechargeable lithium batteries[J].Solid state ionics,2002(3/4):283-289. |
[7] | Andersson A S;Thomas O;Kalska B et al.[J].Electrochemical and Solid-State Letters,2000,3(02):66-68. |
[8] | Prosini PP.;Lisi M.;Zane D.;Pasquali M. .Determination of the chemical diffusion coefficient of lithium in LiFePO4[J].Solid state ionics,2002(1/2):45-51. |
[9] | Ravet N;Chouinard Y;Magnan J F et al.[J].Journal of Power Sources,2001,97-98:503-507. |
[10] | Takahashi M;Tobishima S;Takei K et al.[J].Journal of Power Sources,2001,97-98:508-511. |
[11] | Yang S;Zavalij P Y;Whittingham M S .[J].Electrochemistry Communications,2001,3:505-508. |
[12] | Yang S F;Song Y;Zavalij P Y et al.[J].Electrochemistry Communications,2002,4:239-244. |
[13] | Croce F;Epifanio A D et al.[J].Electrochemical and Solid-State Letters,2002,5(03):A47-A50. |
[14] | Prosini P P;Lisi M et al.[J].Journal of the Electrochemical Society,2002,149(03):A297-A301. |
[15] | Prosini P P;Carewska M;Scaccia S et al.[J].Journal of the Electrochemical Society,2002,149(07):A886-A890. |
[16] | Barker J;Saidi M Y;Swoyer J L .[J].Electrochemical and Solid-State Letters,2003,6(03):A53-A55. |
[17] | Masashi Higuchi;Keiichi Katayama;Yasuo Azuma;Megumi Yukawa;Manabu Suhara .Synthesis of LiFePO_4 cathode material by microwave processing[J].Journal of Power Sources,2003(119/121):258-261. |
[18] | Tarascon J M;Armand M .[J].Nature,2001,414:359-367. |
[19] | Prosini P P;Zane D;Pasquali M .[J].Electrochimica Acta,2001,46:3517-3523. |
[20] | Huang H;Yin S C;Nazar L F .[J].Electrochemical and Solid-State Letters,2001,4(10):A170-A172. |
[21] | 施志聪,李晨,杨勇.LiFePO4新型正极材料电化学性能的研究[J].电化学,2003(01):9-14. |
[22] | Chen Zhaohui;Dahn J R .[J].Journal of the Electrochemical Society,2002,149(09):A1184-A1189. |
[23] | Chung S Y;Bloking J T;Chiang Y-M .[J].Nature Materials,2002,1:123-128. |
[24] | Thackeray Michael .[J].Nature Materials,2002,1:81-82. |
[25] | Iltchev Nick;Chen Yike;Okada Shigeto et al.[J].Journal of Power Sources,2003,119-121:749-754. |
[26] | Yang Shoufeng;Song Yanning et al.[J].Journal of Power Sources,2003,119-121:239-246. |
[27] | Sylvain Franger;Frederic Le Cras;Carole Bourbon;Helene Rouault .Comparison between different LiFePO_4 synthesis routes and their influence on its physico-chemical properties[J].Journal of Power Sources,2003(119/121):252-257. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%