功能材料, 2013, 44(4): 590-594.
PVA-PAA-KOH碱性聚合物电解质膜的制备及其性能
陆霞 1, , 吴仁香 2, , 朱云峰 {"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"研究了3种具有不同组成的氧化银(Ⅰ)电极在2种不同扫速条件下的循环伏安(CV)行为,发现在较慢扫速(0.5 mV/s)条件下,不同组成电极的峰形相差较大. 各电极的峰电流值都呈现出明显的差异,即具有合适配比的混配电极展示出良好的循环可逆性能,而纯纳米粒子组成的电极接受电荷的能力明显较弱. 对于各电极峰位的偏移及峰电流的涨消做了对比解析,表明最佳混配电极中的电活性粒子具有合理的分布,电极极化小,活性物质利用率高,因而能够展示出良好的电化学性能.","authors":[{"authorName":"刘洪涛","id":"080f95aa-c9e2-43ba-8f89-37ac90dafff2","originalAuthorName":"刘洪涛"},{"authorName":"夏熙","id":"787b8e8c-31ba-46d8-92d0-8820bb753c95","originalAuthorName":"夏熙"}],"doi":"10.3969/j.issn.1000-0518.2002.05.008","fpage":"441","id":"0f6fbc0b-a407-426d-98ce-fc2dbc25780a","issue":"5","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"dc271fc9-e9f1-42d8-9fa6-775e0158911d","keyword":"纳米氧化银","originalKeyword":"纳米氧化银"},{"id":"2cc942df-f796-4089-9661-a966daee2955","keyword":"循环伏安","originalKeyword":"循环伏安"},{"id":"0e7908e5-dec2-4957-9764-3d7701d90374","keyword":"混配电极","originalKeyword":"混配电极"},{"id":"c306f0a1-5114-41e1-94c8-9c9f655f7443","keyword":"循环可逆性","originalKeyword":"循环可逆性"}],"language":"zh","publisherId":"yyhx200205008","title":"电极用纳米Ag2O的电化学性能研究Ⅲ.电极的循环伏安行为","volume":"19","year":"2002"},{"abstractinfo":"随着电缆在配电网中的大量应用,系统电容电流水平不断提高,准确便捷地测量配电网系统对地电容电流成为研究领域的热点.介绍了常用的对地电容电流的测量方法以及估算方法,针对现实中存在的对地电容电流的测量不准确现象,分析了影响准确测量电容电流的原因,提出了增强中性点非直接接地系统电容电流测量准确性的措施.","authors":[{"authorName":"杨湛晔","id":"ab531e30-4b51-48e9-9642-fad2f57b5543","originalAuthorName":"杨湛晔"},{"authorName":"孙岩洲","id":"991b8c1d-0884-425e-a73f-c69a082aee7a","originalAuthorName":"孙岩洲"},{"authorName":"荆国胜","id":"8913c23a-5317-454e-9a92-b0d94c98aaf3","originalAuthorName":"荆国胜"},{"authorName":"吕国栋","id":"c78d050f-d615-4821-ac70-a3d8b43cb472","originalAuthorName":"吕国栋"}],"doi":"10.3969/j.issn.1009-9239.2008.03.021","fpage":"69","id":"c4306eda-9390-4933-9395-f083190f15ae","issue":"3","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"7f4a2f5a-9616-4b69-b463-3365a4e13637","keyword":"配电网系统","originalKeyword":"配电网系统"},{"id":"40b65f1e-5069-4778-bc4c-570cdf6620ac","keyword":"电容电流","originalKeyword":"电容电流"},{"id":"1a6bc0b7-b8dc-4bba-b395-fcc44d40865d","keyword":"电缆","originalKeyword":"电缆"},{"id":"372512ab-00bd-4eb1-8c4c-88bf3a0ccab8","keyword":"测量","originalKeyword":"测量"}],"language":"zh","publisherId":"jycltx200803021","title":"配电网电容电流测量准确性研究","volume":"41","year":"2008"},{"abstractinfo":"介绍了适用于输配电铜及铜合金件镀银工艺,其流程主要包括化学除油、盐酸活化、混酸酸洗、氰化镀铜、氰化镀银、电解钝化.说明了各工艺的操作条件及注意事项.给出了银镀层变色后的处理,不合格品的褪镀方法,以及镀层抗变色性能、结合力和显微硬度的测试方法.指出了该工艺对环保方面的要求.针对实际生产中遇到的漏镀和镀层有少量颗粒的问题,提出了改进措施.","authors":[{"authorName":"茅红裕","id":"b09c141f-2e33-49fb-a478-3f10fd5179d1","originalAuthorName":"茅红裕"}],"doi":"","fpage":"8","id":"55cbdfb1-53cf-4d8d-9cc1-4ce248269fcb","issue":"6","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"ca50b696-f8e0-4ff4-bcc8-02435f379abc","keyword":"铜","originalKeyword":"铜"},{"id":"b32101db-f9fa-4010-be05-6acdb393c495","keyword":"镀银","originalKeyword":"镀银"},{"id":"e4602865-abaa-45a1-af05-35ac7c303883","keyword":"后处理","originalKeyword":"后处理"},{"id":"688ea9ee-bed1-406e-89a6-3fa0b6dd2de2","keyword":"逆流水洗","originalKeyword":"逆流水洗"},{"id":"01e88a16-0c1b-44e4-bfa9-56982f87f932","keyword":"防变色","originalKeyword":"防变色"},{"id":"f15ceb38-b7d7-4ee4-99fc-c470c2332288","keyword":"烘烤","originalKeyword":"烘烤"},{"id":"e159cd18-2629-4e7a-82ec-1405af8a1abe","keyword":"褪镀","originalKeyword":"褪镀"}],"language":"zh","publisherId":"ddyts201106003","title":"适用于输配电行业的铜件镀银工艺","volume":"30","year":"2011"},{"abstractinfo":"本文将石墨、TiO2纳米晶以及TiO2胶体共混,采用旋涂法制备了碳薄膜对电极,并用于组装染料敏化太阳能电池.采用场发射扫描电子显微镜观察薄膜的表面形貌,采用四探针电阻率测试仪、电化学交流阻抗图谱及太阳能电池综合测试仪对碳对电极的电学、电化学性质以及电池的光电性能分别进行测试;研究了薄膜厚度对碳对电极导电性能与电化学催化性能的影响.结果表明随着厚度增加,碳对电极的方块电阻和界面电荷传输电阻均变小,分别可达到26.6Ω.sP -1和11.8Ω.cm-2,而电池的填充因子及光电转换效率增大.当碳薄膜厚度为19.5μm时,光电转换效率可达到Pt对电极的70％.","authors":[{"authorName":"童思超","id":"fab89327-8237-4e76-97e7-e75dbe3bf324","originalAuthorName":"童思超"},{"authorName":"杨兵初","id":"9d79fd33-8645-4058-9125-8f433f763bc2","originalAuthorName":"杨兵初"},{"authorName":"周聪华","id":"c43157a9-afe3-414c-83b1-5a76b7e9e59e","originalAuthorName":"周聪华"},{"authorName":"王丽丽","id":"287364d6-7cf0-4683-974b-eaf95fb9dd11","originalAuthorName":"王丽丽"},{"authorName":"张亚","id":"0fdea96d-71fa-467c-a511-9a36d5bde7d7","originalAuthorName":"张亚"},{"authorName":"张峰杰","id":"6d7b81df-951d-4022-b6e2-f2a4df64da69","originalAuthorName":"张峰杰"}],"doi":"10.3969/j.issn.1007-4252.2012.02.006","fpage":"122","id":"f20ff0a8-43a0-408e-8322-449a143aa3e3","issue":"2","journal":{"abbrevTitle":"GNCLYQJXB","coverImgSrc":"journal/img/cover/GNCLYQJXB.jpg","id":"34","issnPpub":"1007-4252","publisherId":"GNCLYQJXB","title":"功能材料与器件学报 "},"keywords":[{"id":"3e13dfbf-54b9-4b6c-b742-96545c9a3f21","keyword":"染料敏化太阳能电池","originalKeyword":"染料敏化太阳能电池"},{"id":"cde9515f-e5e7-4ced-a5d0-2d5cbb552328","keyword":"对电极","originalKeyword":"对电极"},{"id":"005baba0-0168-43ca-88a7-bd267dbad8bd","keyword":"石墨","originalKeyword":"石墨"},{"id":"509da63a-b09e-4aa8-a667-8c0d33a3f051","keyword":"方块电阻","originalKeyword":"方块电阻"},{"id":"f291dc54-359d-4ffd-be65-45b8261dc404","keyword":"界面电荷传输电阻","originalKeyword":"界面电荷传输电阻"}],"language":"zh","publisherId":"gnclyqjxb201202006","title":"石墨/TiO2共混碳薄膜对电极的电学与电化学性能研究","volume":"18","year":"2012"},{"abstractinfo":"在介绍国外的非晶合金配电变压器应用现状的背景下,对我国的非晶合金配电变压器应用现状进行分析,并对它的发展提出一些建议.","authors":[{"authorName":"徐泽玮","id":"31c35e91-97ec-4452-962a-6a5e751fad88","originalAuthorName":"徐泽玮"}],"doi":"10.3969/j.issn.1005-8192.2006.03.008","fpage":"29","id":"0f254c9b-351a-4495-a200-8fa61e0c49f8","issue":"3","journal":{"abbrevTitle":"JSGNCL","coverImgSrc":"journal/img/cover/JSGNCL.jpg","id":"46","issnPpub":"1005-8192","publisherId":"JSGNCL","title":"金属功能材料"},"keywords":[{"id":"b326c290-2a0a-4649-b43e-19bcf24c18e3","keyword":"非晶合金配电变压器","originalKeyword":"非晶合金配电变压器"},{"id":"fcdea8a3-4249-4a16-b82c-47e8305f1803","keyword":"应用","originalKeyword":"应用"},{"id":"e9a2abd4-447c-4bda-a0e4-775d2e916a6f","keyword":"发展","originalKeyword":"发展"}],"language":"zh","publisherId":"jsgncl200603008","title":"我国非晶合金配电变压器的应用现状和发展建议","volume":"13","year":"2006"},{"abstractinfo":"利用电沉积法在氰桥混配物预修饰的玻璃碳电极上再沉积CuInSe2半导体材料,制备了一种复合型修饰光电极( Eu-Fe-Mo/CuInSe2).以含Cu2+、In3+、SeO2-3及柠檬酸钠的酸性水溶液为电镀液,通过优化寻找到电镀液中最佳的Cu∶ In∶ Se料液比例,用恒电位电沉积法可以制备出具有良好光电效应的复合型修饰光电极.用SEM、EDS技术对复合修饰光电极的表面形貌及其修饰材料的元素组成进行了表征;以60W的普通日光型白炽灯为光源,采用开路电压和计时安培法研究了该复合修饰光电极的光电性质.测得该光电极的响应光电压大于30 mV,响应光电流密度大于8.9×10-6 A/cm2.实验结果表明,该复合修饰光电极呈现典型p型半导体的光电性质.","authors":[{"authorName":"李婷婷","id":"e5480fe6-6508-42e8-9af5-df5ecbe061e3","originalAuthorName":"李婷婷"},{"authorName":"马永钧","id":"afa58bdd-c39b-4289-95b6-b78aa7a0a39c","originalAuthorName":"马永钧"},{"authorName":"刘婧","id":"64df00b6-5278-4d14-8f61-26d7d9bcc326","originalAuthorName":"刘婧"},{"authorName":"何春晓","id":"50076a58-e10a-4764-b958-ee5f02285a4a","originalAuthorName":"何春晓"},{"authorName":"周敏","id":"bb5e23ab-2772-4bde-825b-2b4f13c6b479","originalAuthorName":"周敏"},{"authorName":"彭波","id":"88d3eccb-cf5f-4de9-8482-40f9adeb4730","originalAuthorName":"彭波"}],"doi":"10.3724/SP.J.1095.2012.00405","fpage":"954","id":"4beb7ba1-9f3a-496f-8fe6-23d7f977a4a2","issue":"8","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"3c6325df-ee6c-4b2b-8fde-a972f9031188","keyword":"CuInSe2","originalKeyword":"CuInSe2"},{"id":"ace34027-d76c-44fe-a4a4-da760bd3b4d4","keyword":"光电极","originalKeyword":"光电极"},{"id":"761dba35-ab07-4b95-8b0c-f15e63fc46f7","keyword":"光电性质","originalKeyword":"光电性质"},{"id":"56aebad1-c51e-484c-a53e-303361b00104","keyword":"氰桥混配物","originalKeyword":"氰桥混配物"}],"language":"zh","publisherId":"yyhx201208018","title":"CuInSe2/氰桥混配物复合修饰光电极的制备及其光电性质","volume":"29","year":"2012"},{"abstractinfo":"本文介绍日本为完成1997年\"京都议定书\"对其温室气体减排量的指标要求,大力开发应用超高效节能配电变压器(DT)和铁芯材料的发展情况.","authors":[{"authorName":"陈国钧","id":"7fa98fdf-4232-4ca9-b5c3-2fe169ee375a","originalAuthorName":"陈国钧"},{"authorName":"彭伟锋","id":"b27a0939-35ff-4809-bcac-1047556057fc","originalAuthorName":"彭伟锋"},{"authorName":"桑灿","id":"34500122-8024-4577-b7b7-a3d2a7d4ed3e","originalAuthorName":"桑灿"},{"authorName":"吕建","id":"be988a24-27c6-427e-bdad-47bfd9a126c2","originalAuthorName":"吕建"},{"authorName":"涂国超","id":"905d2e14-3416-46fa-97d0-ca6e49b29dc8","originalAuthorName":"涂国超"},{"authorName":"降向东","id":"799c3e1a-cd38-4e32-8a0e-8ef5eb7d92fb","originalAuthorName":"降向东"},{"authorName":"董哲","id":"15373faf-b81b-49e2-a4f8-9ca77dc97cb9","originalAuthorName":"董哲"}],"doi":"10.3969/j.issn.1005-8192.2007.03.010","fpage":"41","id":"2cb3c524-09f7-4bb4-96d3-7eaa8a6bd3a7","issue":"3","journal":{"abbrevTitle":"JSGNCL","coverImgSrc":"journal/img/cover/JSGNCL.jpg","id":"46","issnPpub":"1005-8192","publisherId":"JSGNCL","title":"金属功能材料"},"keywords":[{"id":"5a43b2a8-370e-4897-81b1-02e7758075bc","keyword":"温室气体","originalKeyword":"温室气体"},{"id":"91ba562a-6816-4dba-8cdd-afec99b5ea10","keyword":"配电变压器","originalKeyword":"配电变压器"},{"id":"2cdbdfe4-3021-4b9e-877d-7b9a096bf148","keyword":"节能","originalKeyword":"节能"},{"id":"2c086e60-baea-4d7d-a022-75c4a6340a00","keyword":"超低铁损铁芯材料","originalKeyword":"超低铁损铁芯材料"}],"language":"zh","publisherId":"jsgncl200703010","title":"高效节能配电变压器的开发和铁芯材料的发展","volume":"14","year":"2007"},{"abstractinfo":"对珠钢220 kV总降站1号33 kV配电系统在运行中表现出来的主要问题进行浅析,改进总降33 kV系统,确保安全、可靠运行.","authors":[{"authorName":"陈木华","id":"1fe5821f-6142-4ff1-bd82-bbbe6faba53b","originalAuthorName":"陈木华"},{"authorName":"曾敏","id":"d4d2aafc-d6d2-4d21-a892-dc316add67b2","originalAuthorName":"曾敏"}],"doi":"10.3969/j.issn.1006-9356.2004.11.011","fpage":"43","id":"334ea12f-4b61-48c7-a136-e21b6726b55f","issue":"11","journal":{"abbrevTitle":"ZGYJ","coverImgSrc":"journal/img/cover/ZGYJ.jpg","id":"87","issnPpub":"1006-9356","publisherId":"ZGYJ","title":"中国冶金"},"keywords":[{"id":"e40d8e6d-8521-46f3-8066-4a8e5b97ffd4","keyword":"继电保护","originalKeyword":"继电保护"},{"id":"41932667-f45c-4781-bb5c-91a14f13c81b","keyword":"功率因数","originalKeyword":"功率因数"},{"id":"3043057e-61fe-445a-b3ab-8a722448a1d8","keyword":"国产化","originalKeyword":"国产化"}],"language":"zh","publisherId":"zgyj200411011","title":"浅谈珠钢1号电炉33kV配电系统改造","volume":"","year":"2004"},{"abstractinfo":"介绍了近几年Fe-Si-B非晶合金作为配电变压器铁芯材料,在降低铁芯损耗、降低激磁功率、提高工作磁感、改善带材脆性等方面的最新专利信息.","authors":[{"authorName":"李志华","id":"25e3ea55-2294-490d-8384-7df3648e18d0","originalAuthorName":"李志华"}],"doi":"10.3969/j.issn.1005-8192.2000.05.004","fpage":"16","id":"70888b30-f2ca-46fe-98a9-82334f48d81e","issue":"5","journal":{"abbrevTitle":"JSGNCL","coverImgSrc":"journal/img/cover/JSGNCL.jpg","id":"46","issnPpub":"1005-8192","publisherId":"JSGNCL","title":"金属功能材料"},"keywords":[{"id":"ffd23600-abcf-45f5-8bad-17982f307c3a","keyword":"铁基合金","originalKeyword":"铁基合金"},{"id":"f5939a5e-d048-410f-8001-7e4a7b7acb38","keyword":"非晶合金","originalKeyword":"非晶合金"},{"id":"1325dab0-58a1-4a49-81af-1af922e96c89","keyword":"配电变压器","originalKeyword":"配电变压器"}],"language":"zh","publisherId":"jsgncl200005004","title":"配电变压器用铁基非晶合金最新进展","volume":"7","year":"2000"},{"abstractinfo":"经过20多年的努力，国产化非晶合金配电变压器条件已经成熟，国产化非晶合金材料和铁芯生产基地已经建立，利用国产化铁芯已经设计出油浸式三相和单相、干式三相和单相非晶合金配电变压器系列。为了进一步降低非晶合金配电变压器的成本，提高性能，对非晶合金材料提出了提高工作磁通密度、增加填充系数、适当降低脆性、减少磁致伸缩系数等要求。","authors":[{"authorName":"徐泽玮","id":"99147687-d709-433d-8bb7-4a6c1d371af1","originalAuthorName":"徐泽玮"}],"doi":"10.3969/j.issn.1005-8192.2000.06.001","fpage":"1","id":"aa555726-2de5-4e19-9926-b60f1737eafa","issue":"6","journal":{"abbrevTitle":"JSGNCL","coverImgSrc":"journal/img/cover/JSGNCL.jpg","id":"46","issnPpub":"1005-8192","publisherId":"JSGNCL","title":"金属功能材料"},"keywords":[{"id":"d12645f8-8a3b-41bc-b811-3083546ac2c7","keyword":"非晶合金","originalKeyword":"非晶合金"},{"id":"f964bbf0-3c8b-473f-8604-78d910aa8fbc","keyword":"配电变压器","originalKeyword":"配电变压器"},{"id":"bf9fdfea-027f-49e1-b1b8-7665c52f0dc4","keyword":"国产化","originalKeyword":"国产化"}],"language":"zh","publisherId":"jsgncl200006001","title":"非晶合金配电变压器国产化和对材料的要求","volume":"7","year":"2000"}],"totalpage":973,"totalrecord":9726}