过氧乙酸氧化三乙烯基POSS单体制备POSS环氧化物,通过NMR、FT-IR分析POSS环氧化前后结构的变化,研究并讨论了H2O2浓度、乙酸含量、反应温度、反应时间对三乙烯基POSS环氧化反应的影响.结果表明,三乙烯基POSS环氧化的适宜条件是:H2O2的质量分数为50%,反应温度70 ℃,CH3COOH∶H2O2=0.5∶1,反应时间5 h.
参考文献
| [1] | Fu B X;Gelfer M Y;Hsiao B S.[J].Polymer:1499-1506. |
| [2] | Li G Z;Wang L C;Ni H L.[J].Journal of Inorganic and Organometallic Polymers,2001:123-154. |
| [3] | Fu B X;Hsiao B S;White H.[J].Polymer International:437-440. |
| [4] | Timothy S H;Patrick T M;Hong G J.[J].Materials Research Society Symposium Proceedings:261-267. |
| [5] | Lee J S;Lichtenhan J D.[J].Macromolecules:4970-4974. |
| [6] | Xu H Y;Kuo S W;Lee J S.[J].Polymer:5117-5124. |
| [7] | Jeon H G;Mather P T;Haddad T S.[J].Polymer International:453-457. |
| [8] | Li G Z;Wang L C;Toghiani G.[J].Macromolecules:8686-8693. |
| [9] | Li G Z;Wang L;Toghiani H.[J].PLOYMER:4167-4176. |
| [10] | Harris M;Chaudhary T;Drzal L.[J].Materials Science and Engineering A:223-236. |
| [11] | Zhang CX.;Laine RM. .SILSESQUIOXANES AS SYNTHETIC PLATFORMS .2. EPOXY-FUNCTIONALIZED INORGANIC-ORGANIC HYBRID SPECIES[J].Journal of Organometallic Chemistry,1996(1/2):199-201. |
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