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  4. 含糖聚合物的化学合成研究进展

材料导报, 2012, 26(21): 83-88.

含糖聚合物的化学合成研究进展

吴敏捷 1, , 周志平 2, , 戴晓晖 3,

1.江苏大学材料科学与工程学院,镇江212013

2.江苏大学材料科学与工程学院,镇江212013

3.江苏大学材料科学与工程学院,镇江212013

基金项目:   国家自然科学基金(21004031,21174057)  

关键词： 含糖聚合物 , 离子聚合法 , 大分子反应法 , 可控/活性自由基聚合法

Rearch Progress on the Chemical Synthesis of Polymers Containing Sugar Moieties

概述了化学合成法制备含糖聚合物的研究进展,介绍了可控/活性自由基聚合诸方法的机理,详细比较了离子聚合法、可控/活性自由基聚合法、大分子反应法在含糖聚合物合成应用中的优缺点.

参考文献

[1] Ladmiral V.;Melia E.;Haddleton DM. .Synthetic glycopolymers: an overview [Review][J].European Polymer Journal,2004(3):431-449.
[2] Spain SG;Gibson MI;Cameron NR .Recent advances in the synthesis of well-defined glycopolymers[J].Journal of Polymer Science, Part A. Polymer Chemistry,2007(11):2059-2072.
[3] Yang, Q.;Ulbricht, M. .Cylindrical membrane pores with well-defined grafted linear and comblike glycopolymer layers for lectin binding[J].Macromolecules,2011(6):1303-1310.
[4] Stacy S;James B;David H M et al.Synthesis of glycopolymers via click reactions[J].European Polymer Journal,2010,47:435.
[5] Vijayakumar GR;Lohith K;Somashekar BR;Divakar S .Lipase catalyzed synthesis of L-alanyl, L-leucyl and L-phenylalanyl esters of D-glucose using unprotected amino acids[J].Biotechnology Letters,2004(17):1323-1328.
[6] Hut YM;Ju LK .Lipase-mediated deacetylation and oligomerization of lactonic sophorolipids[J].Biotechnology Progress,2003(2):303-311.
[7] 杨光,范晓东,田威,穆承广,程广文."活性"/可控自由基聚合制备含糖聚合物的研究进展[J].高分子材料科学与工程,2011(06):182-185,190.
[8] 田静,万灵书,徐志康.含糖聚合物可控合成研究进展[J].化学通报（印刷版）,2008(02):102-109.
[9] Szwarc M;Levy M;Milkovich R .Polymerization initiated by electron transfer to monomer.A new method of formation of block polymerization[J].Journal of the American Chemical Society,1956,78(11):2556.
[10] Jin-Shan Wang;Krzysztof Matyjaszewski .Controlled/'Living' Radical Polymerization. Atom Transfer Radical Polymerization in the Presence of Transition-Metal Complexes[J].Journal of the American Chemical Society,1995(20):5614-5615.
[11] Wang J S;Matyjaszewski K ." Living"/Controlled radical polymerization.Transition-metal-catalyed atom transfer radical polymerization in the presence of a conventional radical initiator[J].Macromolecules,1995,28(22):7572.
[12] Kato M;Kamigaito M;Sawamoto M et al.Polymerization of methyl methacrylate with the carbon tetrachloride/dichlorotris-(triphenylphosphine) ruthenium(Ⅱ)/methylaluminum bis(2,6-di-tert-butylphenoxide) initiating system:Possibility of living radical polymerization[J].Macromolecules,1995,28(05):1721.
[13] Krzysztof Matyjaszewski;Jianhui Xia .Atom Transfer Radical Polymerization[J].Chemical Reviews,2001(9):2921-2990.
[14] Le?n, O.;Mu?oz-Bonilla, A.;Bordegé, V.;Sánchez-Chaves, M.;Fernández-García, M. .Amphiphilic block glycopolymers via atom transfer radical polymerization: Synthesis, self-assembly and biomolecular recognition[J].Journal of Polymer Science, Part A. Polymer Chemistry,2011(12):2627-2635.
[15] Zhou W;Dai XH;Dong CM .Biodegradable and biomimetic poly(epsilon-caprolactone)/poly(lactobionarnidoethyl methacrylate) biohybrids: Synthesis, lactose-installed nanoparticles and recognition properties[J].Macromolecular bioscience,2008(3):268-278.
[16] Suriano F .Synthesis of amphiphilic A3B mikto-arm copolymers from a sugar core:Combination of hydrophobic PLC and hydrophilic glycopolymers for biocompatible nanovector preparation[J].Polymer Chemistry,2010,48(15):3271.
[17] Krstina J;Le T;Rizzardo E et al.Living free-radial polymerization by reversible addition-fragmentation chain transfer:The RAFT process[J].Macromolecules,1998,31:5559.
[18] Barner L;Davis TP;Stenzel MH;Barner-Kowollik C .Complex macromolecular architectures by reversible addition fragmentation chain transfer chemistry: Theory and practice[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2007(5):539-559.
[19] Wang, Y.;Li, X.;Hong, C.;Pan, C. .Synthesis and micellization of thermoresponsive galactose-based diblock copolymers[J].Journal of Polymer Science, Part A. Polymer Chemistry,2011(15):3280-3290.
[20] Smith E;Antons S;Giovanna G et al.Diblock glycopolymers promote colloidal stability of polyplexes and effective ρDNA and siRNA delivery under physiological salt and serum conditions[J].Biomacromolecules,2011,12(08):3015.
[21] Escalé, P.;Ting, S.R.S.;Khoukh, A.;Rubatat, L.;Save, M.;Stenzel, M.H.;Billon, L. .Synthetic route effect on macromolecular architecture: From block to gradient copolymers based on acryloyl galactose monomer using RAFT polymerization[J].Macromolecules,2011(15):5911-5919.
[22] Ivin K J;Lam L M;Roone J J .The ring-opening metathesis polymerization of (±)-endo-bicyclo[2.2.1]hept-5-en-2-yl acetate[J].Macromolecules,1993,194(11):3203.
[23] Takasu, A.;Kojima, H. .Synthesis and ring-opening polymerizations of novel S-glycooxazolines[J].Journal of Polymer Science, Part A. Polymer Chemistry,2010(24):5953-5960.
[24] James J.Murphy;Kotohiro Nomura;R.Michael Paton .Synthesis of Isoxazolino Norbornene Derivatives Containing Sugar Residues by 1,3-Dipolar Cycloaddition and Their Application to the Synthesis of Neoglycopolymers by Living Ring-Opening Metathesis Polymerization[J].Macromolecules,2006(9):3147-3153.
[25] Georges M;Veregin R;Kazmaizer P et al.Narrow molecular weight resins by a free-radical polymerization process[J].Macromolecules,1993,26(11):2987.
[26] Ting, SRS;Min, EH;Escale, P;Save, M;Billon, L;Stenzel, MH .Lectin Recognizable Biomaterials Synthesized via Nitroxide-Mediated Polymerization of a Methacryloyl Galactose Monomer[J].Macromolecules,2009(24):9422-9434.
[27] Yoshiko Miura;Daisuke Koketsu;Kazukiyo Kobayashi .Synthesis and properties of a well-defined glycopolymer via living radical polymerization[J].Polymers for advanced technologies,2007(8):647-651.
[28] KENJI YAMADA;MASAHIKO MINODA;TAKESHI FUKUDA;TAKEAKI MIYAMOTO .Amphiphilic Block and Statistical Copolymers with Pendant Glucose Residues: Controlled Synthesis by Living Cationic Polymerization and the Effect of Copolymer Architecture on Their Properties[J].Journal of Polymer Science, Part A. Polymer Chemistry,2001(4):459-467.
[29] Kenji Yamada;Katsushi Yamaoka;Masahiko Minoda;Takeaki Miyamoto .Survey of a catalyst system for living cationic polymerization of glucose-carrying vinyl ethers with acetyl and isopropylidene protecting groups[J].Polymer international,2001(5):531-537.
[30] Ouchi T;Uchida T;Ohya Y .Synthesis of poly(L-lactide)with one terminal D-glucose residue and wettability of its film surface[J].Macromolecular Bioscience,2001,1(09):371.
[31] Le B;Nicolas J .Recent advances in the design of bioconjugates from controlled/living radical polymerization[J].Polymer Chemistry,2010,1:563.
[32] Hartmuth C. Kolb;K. Barry Sharpless .Click chemistry: diverse chemical function from a few good reactions[J].Angewandte Chemie International Edition,2001(11):2004-2021.
[33] Jung K O .Recent advances in controlled/living radical polymerization in emulsion and dispersion[J].Journal of Polymer Science Part A:Polymer Chemistry,2008,46(21):6983.
[34] Jatin Kumar;Lyndal McDowall;Gaojian Chen .Synthesis of thermo-responsive glycopolymers via copper catalysed azide-alkyne 'click' chemistry for inhibition of ricin: the effect of spacer between polymer backbone and galactose[J].Polymer chemistry,2011(8):1879-1886.
[35] Song, Z.;He, X.-P.;Li, C.;Gao, L.-X.;Wang, Z.-X.;Tang, Y.;Xie, J.;Li, J.;Chen, G.-R. .Preparation of triazole-linked glycosylated α-ketocarboxylic acid derivatives as new PTP1B inhibitors[J].Carbohydrate research,2011(1):140-145.
[36] Chen, Y.;Chen, G.;Stenzel, M.H. .Synthesis and lectin recognition of glyco star polymers prepared by "clicking" thiocarbohydrates onto a reactive scaffold[J].Macromolecules,2010(19):8109-8114.
[37] Kristian Kempe;Christine Weber;Krzysztof Babiuch .Responsive Glyco-poly(2-oxazoline)s: Synthesis, Cloud Point Tuning, and Lectin Binding[J].Biomacromolecules,2011(7):2591-2600.
[38] Xue C H;Donuru V R R;Liu H Y et al.Versatile prepolymerization and postpolymerization functionalization approaches for well-defined fluorescent conjugated fluorenebased glycopolymers[J].Macromolecules,2006,39(17):5747.
[39] Keigo A;Katsuhito I;Masahiko O et al.Globular carbohydrate macromolecule "sugar balls",2.Synthesis of mono,(glycopeptide)-persubstituted dendrimers by polymer reaction with sugar-substitude α-amino acid N-carboxganhydrides ,(glycoNCAS)[J].Macromolecular Rapid Communications,1998,19(01):5.
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