采用循环伏安法、开路计时电位法和方波伏安法,在含4.32×10-4 mol/cm3 CeF3的LiF-NaF-KF熔盐(温度873 K)中研究了Ce3+的阴极电化学行为,结果表明,Ce3+的阴极还原是一个一步电子得失的不可逆过程,主要受扩散控制.在上述熔盐中,以Ni为阴极,采用恒电流密度145 mA/cm2电解12h,所得到的电沉积产物为Ce金属以及铈镍合金Ce2Ni7.
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