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不同Sr掺杂量(x)、Mg掺杂量(y)的LaGaO3材料采用固态反应法制备,用XRD进行材料相分析,用交流阻抗法研究了离子导电性.结果表明,不同Sr、Mg掺杂量的LaGaO3材料可由单一的立方相组成,也可由立方相和第二相组成,主要取决于Sr、Mg掺杂量;随x或y的增加,离子电导率σ开始增加,达到极大值后,逐步减小.当x=0.15,y=0.20或x=0.20.y=0.15时具有最高的离子电导率,σ可达刭0.148S/cm;随测试温度的升高,离子电导率σ增加;In(σT)与1/T曲线由两段不同斜率的直线组成;在较低温度下,氧空位扩散的激活能较高.

参考文献

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