欢迎登录材料期刊网

材料期刊网

高级检索

为了改善活性生物稀土梯度涂层的质量,在碱液环境中采用电极化处理法(PAS)对宽带激光熔覆生物活性稀土梯度涂层进行后处理。利用XRD和电化学分析仪对涂层的相组成和耐腐蚀性进行了研究,通过模拟体液浸泡试验考察了生物陶瓷涂层的生物活性和涂层表面的电荷分布情况。结果表明,碱液环境中电极化处理法(PAS)能够提高涂层的结晶度,使涂层中的非晶相、杂相向羟基磷灰石转化。PAS对涂层的耐腐蚀性影响不大。与未处理涂层相比,PAS处理后的涂层生物活性更好,且涂层表面产生了更多的负电荷。

To improve the quality of rare earth active bioceramic gradient coatings,a method of electric polarized treatment(PAS) was used to post-process the gradient coatings fabricated by wide band laser cladding in alkali liquid.The phases and corrosion resistance of the bioceramic coatings were analyzed by XRD and an electrochemical analyzer.The bioceramic coatings were immersed in simulated body fluid(SBF) to examine its bioactivity and its electrical charge.The experimental results indicate that PAS treatment not only improves the crystallinity of the coatings,but also is favourable to transform additional phases into hydroxyapatite.PAS treatment exhibits a little effect on corrosion resistance of the bioceramic coatings.Compared with as-received coatings,the coatings treated by PAS are of better bioactivity and more negative charge.

参考文献

[1] 俞耀庭;张兴栋.生物医用材料[M].天津:天津大学出版社,2000
[2] Y.C. Yang;E. Chang .The bonding of plasma-sprayed hydroxyapatite coatings to titanium: effect of processing, porosity and residual stress[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(1/2):260-275.
[3] Stoch A;Jastrzebski W .Sol-gel derived hydroxyapatite coatings on titanium and its alloy Ti6A14-[J].Molecular structure,2005,22(05):744-747.
[4] Manso M.;Morant C.;Herrero P.;Martinez-Duart JM.;Jimenez C. .Electrodeposition of hydroxyapatite coatings in basic conditions[J].Biomaterials,2000(17):1755-1761.
[5] 王勇,高家诚,张亚平.激光熔覆梯度生物陶瓷涂层的研究[J].中国激光,2004(04):487-490.
[6] 刘其斌,王存山,夏元良.宽带激光熔覆WCp/Ni基合金梯度涂层中WCp的溶解机理[J].材料热处理学报,2001(03):33-36.
[7] 刘其斌;陈江;王丽 等.高温合金激光表面熔铸涂层组织与性能的研究[J].金属热处理学报,1997,18(02):52-54.
[8] 刘其斌,郑敏,朱维东,李海涛,董闯.宽带激光熔覆梯度生物活性陶瓷复合涂层组织与性能[J].应用激光,2004(06):350-354.
[9] 刘其斌,郑敏,朱维东,李海涛,董闯.钛合金表面宽带激光熔覆梯度生物陶瓷复合涂层[J].功能材料,2005(01):50-53.
[10] 黄毅,杨帮成,冯家岷,陈继镛,刘晓光,张兴栋.碱液环境中等离子喷涂羟基磷灰石涂层的电极化后处理研究[J].稀有金属材料与工程,2007(08):1377-1381.
[11] Kokubo T;Takadama H .How useful is SBF in predicting in vivo bone bioactivity?[J].Biomaterials,2006(15):2907-2915.
[12] Lin FH;Hsu YS;Lin SH;Sun JS .The effect of Ca/P concentration and temperature of simulated body fluid on the growth of hydroxyapatite coating on alkali-treated 316L stainless steel.[J].Biomaterials,2002(19):4029-4038.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%