以硫酸铵为电解质,对炭纤维进行连续电化学氧化处理,利用反气相色谱(IGC)研究电化学氧化处理前后的表面能变化,并联系SEM、AFM、XRD、Raman、XPS等测试结果综合分析电化学氧化处理对炭纤维表面性能的影响.研究表明,经电化学氧化处理后,纤维沿抽方向表面沟槽加深加宽,薄弱层被剥除,晶格择优取向遭到破坏;纤维表面活性官能团增多,氧和氮含量分别增加了180%和65%,提高了纤维与树脂的粘结性;纤维表面能提高了3.1倍,与树脂的浸润性得到改善;电化学氧化处理后其复合材料的ILSS达109MPa,已可充分满足实际应用需求.
参考文献
[1] | 贺福;王茂章.碳纤维及其复合材料[M].北京:科学出版社,1997:150. |
[2] | 王茂章.聚丙烯腈基炭纤维[J].新型炭材料,1998(04):79. |
[3] | Hoffman W P;Hurley W C;Owens T W et al.Advantage of the scanning tunneling microscope in documenting chan ges in carbon fibers surface morphology brought about by various surface treatments[J].Materials Science,1991,26(08):4545. |
[4] | 贺福;杨永岗 .碳纤维表面处理的新方法[J].高科技纤维与应用,2000,25(05):30. |
[5] | Pittman C U;Jr Jiang W;Yue Z R et al.Surface area and pore size distribution of microporous carbon fibers prepared by electrochemical oxidation[J].Carbon,1999,37(06):85. |
[6] | Beatrice Lindsay;Marie-Laure Abel;John F.Watts .A study of electrochemically treated PAN based carbon fibres by IGC and XPS[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(12):2433-2444. |
[7] | Park S J;Kim B J .Roles of acidic functional groups of carbon fiber surfaces in enhancing interfacial adhesion behavior[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2005,408(01):269. |
[8] | Liu Jie;Tian Yuli;Chen Yujia et al.A surface treatment technique of electrochemical oxidation to simultaneously improve the interfacial bonding strength and the tensile strength of PAN-based carbon fibers[J].Materials Chemistry and Physics,2010,122(02):548. |
[9] | 胡培贤,温月芳,杨永岗,刘朗.氨化处理对碳纤维表面性能及其复合材料的影响[J].纺织学报,2009(02):18-23. |
[10] | Li Junqing;Huang Yudong;Fu Shaoyun et al.Study on the surface performance of caron fibres irradiated by γ-ray under different irradiation dose[J].Applied Surface Science,2010,256(07):2000. |
[11] | 贾玲,周丽绘,薛志云,齐会民,胡福增.碳纤维表面等离子接枝及对碳纤维/PAA复合材料ILSS的影响[J].复合材料学报,2004(04):45-49. |
[12] | 刘鸿鹏,吕春祥,李永红,杨禹,李开喜,贺福.电化学表面处理PAN基炭纤维的表面性能研究[J].新型炭材料,2005(01):39-44. |
[13] | Febo Severini;Leonardo Formaro;Mario Pegoraro;Luca Posca .Chemical modification of carbon fiber surfaces[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(5):735-741. |
[14] | 侯永平,王浩静,李东风.PAN基高模碳纤维阳极氧化的表面处理[J].化工进展,2007(04):558-562. |
[15] | 杨永岗,赵建国,贺福.气液双效表面处理方法的应用[J].新型炭材料,1999(04):49-52. |
[16] | 郭云霞,刘杰,梁节英.电化学改性PAN基碳纤维表面及其机理探析[J].无机材料学报,2009(04):853-858. |
[17] | Dilsiz Nursel;Wightman J.P. .Surface analysis of unsized and sized carbon fibers[J].Carbon: An International Journal Sponsored by the American Carbon Society,1999(7):1105-1114. |
[18] | 姜再兴,黄玉东,刘丽.粗糙度对碳纤维/聚芳基乙炔复合材料界面性能的影响[J].化学与黏合,2007(05):305-308. |
[19] | Lee Jingyong;Lawrence T Drzal .Surface characterization and adhesion of carbon fibers to epoxy and polycarbonate[J].Adhesion and Adhesives,2005,25(05):389. |
[20] | 宋焕成;赵时熙.聚合物基复合材料[M].北京:国防工业出版社,1997 |
[21] | 贺福.碳纤维及石墨纤维[M].北京:化学工业出版社,2010:285. |
[22] | Santos JMRCA;Guthrie JT .Analysis of interactions in multicomponent polymeric systems: The key-role of inverse gas chromatography[J].Materials Science & Engineering, R. Reports: A Review Journal,2005(3):79-107. |
[23] | Schultz J;Lavielle L;Martin C J .The role of the interface in carbon fibre-epoxy composites[J].Journal of Adhesion,1987,23(01):45. |
[24] | Piedad Ganan;Saioa Garbizu;Rodrigo Llano-Ponte;Inaki Mondragon .Surface Modification of Sisal Fibers:Effects on the Mechanical and Thermal Properties of Their Epoxy Composites[J].Polymer Composites,2005(2):121-127. |
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