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以Sm2O3、La2O3和ZrO2为原料,用固相反应法制备了(La0.75Sm0.25)2Zr2O7陶瓷材料.采用XRD和FT-IR技术研究了试样的相结构,用SEM分析了试样的微观组织结构,采用激光脉冲法测量试样的热导率.结果表明,所制备的陶瓷材料具有焦绿石晶体结构,其组织结构致密,晶粒大小均匀,晶界清晰.由于La3+和Sm3+质量和离子半径的差别, (La0.75Sm0.25)2Zr2O7具有比La2Zr2O7更低的热导率.其热导率明显低于现役的YSZ陶瓷,可用作新型热障涂层表面陶瓷层候选材料.

参考文献

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