欢迎登录材料期刊网

材料期刊网

高级检索

采用沉积-沉淀法制备了Au/TiO2光催化剂,并用紫外-可见漫反射光谱和X射线光电子能谱对其进行了表征,详细考察了室温水汽的引入对Au/TiO2光催化分解臭氧活性的影响.结果表明,同干燥状态时相比,室温引入水汽后催化剂活性较低,并且较快地达到了稳定值.催化剂的O 1s和Au 4f的XPS分析结果表明,水汽的存在导致TiO2的表面结构发生变化,进而使金-载体之间的相互作用力减弱.这是导致催化剂活性下降的主要原因.

参考文献

[1] Thompson A M .[J].Science,1992,256(5060):1157.
[2] Lin J J;Kawai A;Nakajima T .[J].Applied Catalysis B:Environmental,2002,39(02):157.
[3] 余家国,熊建锋,程蓓.高活性二氧化钛光催化剂的低温水热合成[J].催化学报,2005(09):745-749.
[4] 尤先锋,陈锋,张金龙,黄家桢,张利中.银促进的TiO2光催化降解甲基橙[J].催化学报,2006(03):270-274.
[5] Ohtani B;Zhang S W;Nishimoto S;Kagiya T .[J].Journal of the Chemical Society,Faraday Transactions,1992,88(07):1049.
[6] Ohtani B;Zhang S W;Ogita T;Nishimoto S Kagiya T .[J].Journal of Photochemistry and Photobiology A:Chemistry,1993,71(02):195.
[7] 贺攀科,杨建军,杨冬梅,王晓辉,张敏.Au/TiO2光催化分解臭氧[J].催化学报,2006(01):71-74.
[8] Haruta M;Yamada N;Kobayashi T;Iijima S .[J].Journal of Catalysis,1989,115(02):301.
[9] Bond G C;Thompson D T .[J].Catalysis Review:Science and Engineering,1999,41(3-4):319.
[10] Hao Z P;Cheng D Y;Guo Y;Liang Y H .[J].Applied Catalysis B:Environmental,2001,33(03):217.
[11] Park E D;Lee J S .[J].Journal of Catalysis,1999,186(01):1.
[12] Cunningham D;Vogel W;Haruta M .[J].Catalysis Letters,1999,63(1-2):43.
[13] Date M;Haruta M .[J].Journal of Catalysis,2001,201(02):221.
[14] Date M;Ichihashi Y;Yamashita T;Chiorino A Boccuzzi F Haruta M .[J].Catalysis Today,2002,72(1-2):89.
[15] Bollinger M A;Vannice M A .[J].Applied Catalysis B:Environmental,1996,8(04):417.
[16] Grunwaldt J D;Kiener C;Wogerbauer C;Baiker A .[J].Journal of Catalysis,1999,181(02):223.
[17] Liu H C;Kozlov A;Kozlova A P;Shido T Iwasawa Y .[J].Physical Chemistry Chemical Physics,1999,1(11):2851.
[18] Yang J H;Henao J D;Raphulu M C;Wang Y M Caputo T Groszek A J Kung M C Scurrell M S Miller J T Kung H H .[J].Journal of Physical Chemistry B,2005,109(20):10319.
[19] Haruta M .[J].Gold Bulletin,2004,37(1-2):27.
[20] Li W C;Comotti M;Schüth F .[J].Journal of Catalysis,2006,237(01):190.
[21] He PK;Zhang M;Yang DM;Yang JJ .Preparation of Au-loaded TiO2 by photochemical deposition and ozone photocatalytic decomposition[J].Surface review and letters,2006(1):51-55.
[22] Jana N R;Gearheart L;Murphy C J .[J].Langmuir,2001,17(22):6782.
[23] Zanella R;Giorgio S;Shin C H;Henry C R Louis C .[J].Journal of Catalysis,2004,222(02):357.
[24] 贺攀科 .[D].开封:河南大学,2006.
[25] Dhandapani B;Oyama S T .[J].Applied Catalysis B:Environmental,1997,11(02):129.
[26] Li W.;Oyama ST.;Gibbs GV. .Mechanism of ozone decomposition on a manganese oxide catalyst. I. In situ Raman spectroscopy and ab initio molecular orbital calculations[J].Journal of the American Chemical Society,1998(35):9041-9046.
[27] 毛立群,冯彩霞,金振声,张治军,党鸿辛.Au/TiO2的制备及其光催化氧化丙烯的研究[J].感光科学与光化学,2005(01):61-65.
[28] Arrii S;Morfin F;Renouprez A J;Rousset J L .[J].Journal of the American Chemical Society,2004,126(04):1199.
[29] Wang G Y;Lian H L;Zhang W X;Jiang D Z Wu T H .[J].Kinetics and Catalysis,2002,43(03):433.
[30] 邹旭华,齐世学,索掌怀,安立敦,李峰.CO低温氧化Au/Al2O3催化剂的失活及稳定性[J].催化学报,2006(02):161-165.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%