欢迎登录材料期刊网

材料期刊网

高级检索

全固态薄膜锂充电电池由于安全可靠性强、能量密度大、工作电压高、循环寿命长等诸多优点已经成为微型电子器件匹配电源的良好选择.阴极、阳极、固体电解质材料是全固态薄膜锂充电电池的重要组成部分,对于其开发和研究十分重要.综述了目前应用较多的阴极、阳极及固体电解质材料,并阐述了其物理特性、电化学性能和主要的制备方法;电池结构设计同样影响着整个电池的性能,介绍了电池结构对充放电特性的影响,且展望了其今后的研究热点和发展方向.

With strong security and reliability,high energy density,high voltage,long cycle life and many other advantages,all-solid-state thin film lithium rechargeable batteries have become good choices for micro-electronic devices.Due to the fact that they are the key components of all-solid-state thin film lithium rechargeable batteries,research and development on cathode,anode,and solid electrolyte are of great importance.This paper firstly reviews cathode,anode,as well as solid electrolyte which are recently applied more preferably,and their physical properties,electrochemical properties and the main methods of preparation of them are described.Properties of batteries are also depended on design of the cell structure.Influence on charge and discharge properties because of cell structure is presented and the future development and research focus are expected as well.

参考文献

[1] J.B. Bates;N.J. Dudney;D.C. Lubben;G.R. Gruzalski;B.S. Kwak;Xiaohua Yu;R.A. Zuhr .Thin-film rechargeable lithium batteries[J].Journal of Power Sources,1995(1):58-62.
[2] Kanehori K;Matsumoto K;Miyauchi K et al.Thin-film solid electrolyte and its application to secondary lithium cell[J].Solid State Ionics,1983,9-10:1445.
[3] 曹乾涛,吴孟强,张树人.全固态薄膜锂离子电池正极材料研究进展[J].材料导报,2008(03):19-23.
[4] Bates J.B.;Dudney N.J. .Preferred Orientation of Polycrystalline LiCoO_2 Films[J].Journal of the Electrochemical Society,2000(1):59-70.
[5] Dudney N J;Jang Yi .Analysis of thin-film lithium batteries with cathodes of 50nm to 4μm thick LiCoO2[J].Journal of Power Sources,2003,119:300.
[6] Julien C.;Escobar-Alarcon L.;Haro-Poniatowski E.;Camacho-Lopez MA. .Fabrication of LiCoO2 thin-film cathodes for rechargeable lithium microbatteries[J].Materials Chemistry and Physics,2001(1/3):210-216.
[7] Shokoohi F K;Tarscon J M;Wilkens B J .Fabrication of thin-film LiMn2O4 cathodes for recharge able microbatteries[J].Applied Physics Letters,1991,59(10):1260.
[8] Park YJ.;Kim MK.;Chung HT.;Kim HG.;Kim JG. .Preparation of LiMn2O4 thin films by a sol-gel method[J].Solid state ionics,2000(3/4):203-214.
[9] Bates J B et al.Rechargeable thin-film lithium microbatteries[J].Solid State Techn,1993,36(07):59.
[10] Nakazawa Hiromi;Sano Kimihiro et al.Charge-discharge characteristics of all-solid-state thin-filmed lithium-ion batteries using amorphous Nb2O5 negative electrodes[J].Journal of Power Sources,2007,174:838.
[11] Bates J B;Dudney N J .Method of making an electrolyte for an electrochemical cell[P].US,5512147,1996-04-30.
[12] Baba M;Kumaga N;Kobayash H et al.Fabrication and electrochemical characteristics of all-solid-state lithium-ion batteries using V2O5 thin films for both electrode[J].Electrochemical and Solid-State Letters,1999,2(07):320.
[13] Neudecker B J et al.Battery with an in-situ activation plated lithium anode[P].US,6168884,2001-01-02.
[14] Baba M;Kumagai N et al.Multi-layered Li-ion rechargeable batteries for a high-voltage and high-current solid-state power source[J].Journal of Power Sources,2003,119-121:914.
[15] Nakazawa Hiromi;Sano Kimihiro et al.Fabrication by using a sputtering method and charge-discharge properties of largesized and thin-filmed lithium ion rechargeable batteries[J].Journal of Power Sources,2005,146:758.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%