以内蒙古优质褐煤为原料,KOH为活化剂,采用微波加热活化法制备超级电容器用活性炭,利用低温氮气吸附及恒流充放电、循环伏安等方法测定活性炭的孔结构及其用作电极材料的电化学性能,并与日本商业化超级电容器用活性炭在结构及性能方面进行对比分析.结果表明,在碱炭比为3,微波活化时间为20 min的条件下,可制备出比表面积达2593 m2/g、总孔容达1.685 cm3/g、孔径主要分布在0.5~10 nm之间、中孔率达67.3%、平均孔径为2.61 nm的优质活性炭.该活性炭用作超级电容器电极材料在3mol/L KOH电解液中具有优异的电化学性能,电流密度由50mA/g提高到10 A/g时,其比电容由346F/g降低到273 F/g,显示出良好的功率特性,经1000次循环后,比电容保持率为93.2%.与商业活性炭相比,微波法活性炭的性能更加优良.
参考文献
[1] | A review on electrochemical double-layer capacitors[J].Energy conversion & management,2010(12):2901-2912. |
[2] | Guoping Wang;Lei Zhang;Jiujun Zhang .A review of electrode materials for electrochemical supercapacitors[J].Chemical Society Reviews,2012(2):797-828. |
[3] | Michio Inagaki;Hidetaka Konno;Osamu Tanaike .Carbon materials for electrochemical capacitors[J].Journal of Power Sources,2010(24):7880-7903. |
[4] | Yuen, FK;Hameed, BH .Recent developments in the preparation and regeneration of activated carbons by microwaves[J].Advances in colloid and interface science,2009(1/2):19-27. |
[5] | Mitsuhiro Kubota;Atsushi Rata;Hitoki Matsuda .Preparation of activated carbon from phenolic resin by KOH chemical activation under microwave heating[J].Carbon,2009(12):2805-2811. |
[6] | Li Wei;Zhang Li-bo;Peng Jin-hui;Li Ning;Zhu Xue-yun .Preparation of high surface area activated carbons from tobacco stems with KCO activation using microwave radiation[J].Industrial Crops and Products,2008(3):341-347. |
[7] | Yang, KB;Peng, JH;Srinivasakannan, C;Zhang, LB;Xia, HY;Duan, XH .Preparation of high surface area activated carbon from coconut shells using microwave heating[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2010(15):6163-6169. |
[8] | Wang T H;Tan S;Liang C H .Preparation and characterization of activated carbonfrom wood via microwave-induced ZnCl2 activation[J].Carbon,2009,47(12):1880. |
[9] | 艾艳玲,李铁虎,冀勇斌.微波加热与传统加热制备高比表面活性炭的对比研究[J].西北工业大学学报,2009(04):527-531. |
[10] | Xiaojun He;Yejing Geng;Jieshan Qiu .Effect of activation time on the properties of activated carbons prepared by microwave-assisted activation for electric double layer capacitors[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(5):1662-1669. |
[11] | 成果,谢应波,龙东辉,张睿,凌立成.超级电容器用新型微晶炭的结构及其电容性能[J].华东理工大学学报(自然科学版),2009(06):803-808. |
[12] | Grazyna Gryglewicz;Ewa Lorenc-Grabowska;Grzegorz Lota;Elzbieta Frackowiak .Effect of pore size distribution of coal-based activated carbons on double layer capacitance[J].Electrochimica Acta,2005(5):1197-1206. |
[13] | Frackowiak E .Carbon materials for supercapacitor application[J].Physical chemistry chemical physics: PCCP,2007(15):1774-1785. |
[14] | J.A. Fernandez;S. Tennison;O. Kozynchenko .Effect of mesoporosity on specific capacitance of carbons[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(6):1598-1604. |
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