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在实验室制备各类AlF3掺杂试验阳极, 在测试其基本物理化学性能的基础上, 采用"改进断电流法"进行阳极过电位测试, 研究AlF3添加剂和阳极焙烧温度对阳极过电位的影响.结果表明: 在一定条件下, 阳极中添加AlF3既可降低阳极的空气/CO2反应活性, 也可降低阳极过电位; 受高温脱S等因素的影响, 阳极的电化学活性及其空气/CO2反应活性并未随着焙烧温度的提高相应降低.

参考文献

[1] Thonstad J;Fellner P;Haarberg G M.Aluminium Electrolysis:Fundamentals of the Hall-Heroult Process,3rd ed[M].Dusseldorf:Aluminium-Verlag,2001:162-169.
[2] 刘业翔.功能电极材料[M].长沙:中南工业大学出版社,1996:247-248.
[3] Aanvik M;Solie M;Oye H A.Reactivity and texture of cokes doped with aluminium compounds[A].Warrendale,Pennsylvania:TMS,2000:555-563.
[4] 王洪 .氟化铝阳极糊的研制与应用[J].轻金属,1993,30(06):41-43.
[5] 于亚鑫;邱竹贤;董贞俭 .三氟化铝在炭阳极中的作用[J].轻金属,1998,35(07):45-47.
[6] 赖延清 .铝电解节能节炭的深层研究——炭素阳极电化学活性与空气/CO<,2>反应活性的研究[D].中南大学,2001.
[7] Yang Jianhong,Lai Yanqing,Xiao Jin,Li Jie,Liu Yexiang,J. Thonstad.MEASUREMENT OF ANODIC OVERVOLTAGE BY A MODIFIED CURRENT INTERRUPTION METHOD IN CRYOLITE-ALUMINA MELTS[J].中国有色金属学会会刊(英文版),1999(01):121-127.
[8] Jarek S;Thonstad J.Wetted surface area and polarization potential of carbon anodes in cryolite-alumina melts[A].Warrendale,Pennsylvania:TMS,1987:399-405.
[9] Coster B;Schneider J P.Influence of coke real density in anode reactivity consequence on anode baking[A].Warrendale,Pennsylvania:TMS,1994:583-589.
[10] Braunworth V A;Brown J A;Hollingshead E A.The addition of aluminium fluoride to soderberg paste[A].New York:The Metallurgical Society of AIME,1975:325-360.
[11] SORLIE M;Kuang Z;Thonstad J .Gas reactivity and electrolytic consumption of aluminium cell anodes with aluminium flouride[J].Carbon,1993,31(05):677-682.
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