以DTBA为链转移剂,VSZ和苯乙烯为单体,通过可逆加成断裂链转移(RAFT)聚合合成了嵌段共聚物陶瓷先驱体Polyvinylsilazane-b-Polystyrene (PVSZ-b-PS).利用DLS、TEM、AFM等技术,考察了PVSZ-b-PS在选择性溶剂DMF中自组装成胶束的行为.结果表明,胶束为核-壳结构的球形,其中PVSZ为核、PS为壳,胶束直径70~110nm.PVSZ-b-PS胶束制成的聚合物膜能完整保留胶束的球形特征,800℃热解能制得直径为30~40 nm的纳米陶瓷颗粒.XRD结果表明陶瓷颗粒是SiC结晶相.
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