含羧基有机化合物控制锐钛矿型纳米二氧化钛生长的研究

材料导报, 2005, 19(z1): 74-76.

含羧基有机化合物控制锐钛矿型纳米二氧化钛生长的研究

姜本鹏 ^1, , 殷恒波 ^2, , 姜廷顺 ^3, , 严静 ^4, , 范真 ^5, , 李长生 ^6, , 吴静 ^7,

1.江苏大学化学化工学院,镇江,212013

2.江苏大学化学化工学院,镇江,212013

3.江苏大学化学化工学院,镇江,212013

4.江苏大学化学化工学院,镇江,212013

5.江苏大学化学化工学院,镇江,212013

6.江苏大学化学化工学院,镇江,212013

7.沈阳化工学院化工系,沈阳,110142

基金项目: 江苏省新产品研发基金(200470)

关键词：锐钛矿型纳米二氧化钛 , 偏钛酸 , 羧酸

Size-controlled Synthesis of Anatase TiO2 Nanoparticles by Carboxylic Acid Group-containing Organics

以偏钛酸为起始反应物,羧酸为修饰剂,进行了纳米锐钛矿型二氧化钛的合成研究.有机修饰剂的化学结构对制得的纳米二氧化钛颗粒的平均粒径及粒径分布影响很大.含非极性基团的羧酸有利于生成平均粒径小及粒径分布窄的锐钛矿型纳米二氧化钛.

参考文献

[1]	Blanchard P;Husson M .[P].PCT Int Appl.WO 2003066692,2003.
[2]	Andersson M;Osterlund L;Ljungstrom S et al.[J].Journal of Physical Chemistry B,2002,106:10674.
[3]	Kopidakis N;Benkstein K D;Lagemaat J van de et al.[J].Journal of Physical Chemistry B,2003,107:11307.
[4]	Cassagneau T;Fendler J H;Mallouk T E .[J].Langmuir,2000,16:241.
[5]	Stiller S.;Gers-Barlag H.;Lergenmueller M.;Pflucker F.;Schulz J. Wittern KP.;Daniels R. .Investigation of the stability in emulsions stabilized with different surface modified titanium dioxides[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2004(2/3):261-267.
[6]	Yin H;Wada Y;Kitamura T .[J].Chemistry Letters,2001,334:334.
[7]	Yin H;Wada Y;Kitamura T.[J].Journal of Materials Chemistry,2001(11):1694.
[8]	Yin H;Wada Y;Kitamura T.[J].Journal of Materials Chemistry,2002(12):378.
[9]	Jang H D;Kim S K .[J].Materials Research Bulletin,2001,36:627.
[10]	Lin J.;Lin Y.;Liu P.;Meziani MJ.;Allard LF.;Sun YP. .Hot-fluid annealing for crystalline titanium dioxide nanoparticles in stable suspension[J].Journal of the American Chemical Society,2002(38):11514-11518.
[11]	Liu D;Zhang J;Han B et al.[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2003,227:45.
[12]	Stallings WE.;Lamb HH. .Synthesis of nanostructured titania powders via hydrolysis of titanium isopropoxide in supercritical carbon dioxide[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(7):2989-2994.
[13]	Lim K T;Hwang H S .[J].Langmuir,2004,20:2466.
[14]	Liu H;Yang W;Ma Y et al.[J].Langmuir,2003,19:3001.
[15]	Caruso R A;Antonietti M;Giersig M et al.[J].CHEMISTRY OF MATERIALS,2001,13:1114.
[16]	Wu X;Wang D;Yang S .[J].Journal of Colloid and Interface Science,2000,222:37.
[17]	Warner J C;Morelli A .[P].PCT Int Appl WO 2003008079,2003.
[18]	Cannon A S;Warner J C.6th Annual Green Chemistry and Engineering Conference Proceedings[M].Washington DC,2002
[19]	Arabatzis I M;Falaras P .[J].Nano Letters,2003,3:249.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

含羧基有机化合物控制锐钛矿型纳米二氧化钛生长的研究

Size-controlled Synthesis of Anatase TiO2 Nanoparticles by Carboxylic Acid Group-containing Organics

参考文献