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采用SEM,XRD等手段对钽在氢与氮等离子体中形成的表面层进行了分析.试验表明,在外界参数相同的情况下,H+N等离子体的存在改变了Ta表面在H-O-N气氛中的反应路径,使反应产物由无等离子体时的Ta2O5变成了Ta6N2.57,因此处理后的表面粗糙度比无等离子体时下降了一个数量级;对等离子体的作用机理进行了探讨.认为是等离子体的存在改变了介质成分和Ta表面附近形成的"阴极鞘层”与Ta表面相互作用抑制了粗糙的Ta2O5形成.

参考文献

[1] Honnaker L R .Process of Making Laminated Spinneret[P].US Pat 4054468,1977.
[2] 刘宇中 .Spinneret with Lithium Tantalate[P].CN 86102269A,1986.
[3] ZHANG De-yuan,LU De-ping,LI Fang,CAI Li,Xu Lan-ping,LIN Qin.Kinetic mechanism of anodic oxidation of tantalum in nitrate melts[J].中国有色金属学会会刊,2000(05):695.
[4] Panaioti T A et al.Regularities of Phase Formation on Nitridation of Tantalum-tungsten Alloys in Glow Discharge[J].Metal Science and Heat Treatment,1994,36(5-6):301-307.
[5] Wu JD;Wu CZ;Zhong XX;Song ZM;Li FM;Northwestern Polytech Univ Dept Appl Phys Xian 710072 Peoples R China. .Surface nitridation of transition metals by pulsed laser irradiation in gaseous nitrogen[J].Surface & Coatings Technology,1997(2/3):330-336.
[6] дA Пp окоб oщкини.т .д.Aзоти p овани e T антана[J].Meталловeденкe итepмничe cкаяo бpаб o ткаMe таллoв,1984,5:32-35.
[7] D. Rafaja .Non-metal diffusion coefficients for the Ta-C and Ta-n systems[J].Acta materialia,1998(10):3477-3483.
[8] Wiesenberger H et al.Reactive Diffusion and Phase Equilibria in the V-C, Nb-C, Ta-C, Ta-N Systems[J].Acta Materialia,1998,46(10):651.
[9] Getteret J et al.Das Kubische Tantalmononitrid (B1-Typ) und seine Mischbarkeit mit den Isotypen ubergangs Metallnitriden und-carbiden[J].Monatshefte Fur Chemie,1975,106:113-147.
[10] Lengauer W et al.Electron-probe Microanalysis of Light Elements in Multiphase Diffusion Couples[J].Microchimica Acta,1997,126:279.
[11] Rafaja D et al.Multiphase Layer Growth Kinetics in Finite Gas/solid Diffusion Coupes[J].Acta Materialia,1996,44(12):4835-4844.
[12] Wang TM et al.Structure Changes and Tribological Behaviors of Nitrogen Ion-implanted Tantaluum[J].Nuclear Instruments and Methods in Physics Research B:Beam Interaction with Materials and Atoms,1996,108(03):300-304.
[13] Baba K;Hatada R .Synthesis and Properties of Tantalum Nitride Films Formed by Ion Beam Assisted Deposiion[J].Surface and Coatings Technology,1996,84(1-3):429-433.
[14] Atsumi N;Yoshioka K et al.Nitriding of Transition Metal Powders by Ball Milling in Nitrogen Gas[J].Materials Transactions,1993,34(12):1212-1216.
[15] Boiko B T;Panchekha P A et al.Effects of Nitriding on Volume-porous Tantalum Structure[J].FIZIKA I KHIMIYA OBRABOTKI MATRRIALOV,1990,1:84-89.
[16] 张德元;李放;罗文 .Analysis of Interface Reactions During Plasma Nitriding ofTantalum[J].中国有色金属学会会刊(英文版),2000,2(02):151.
[17] 周孝重;陈大凯.等离子体热处理技术[M].北京:北京工业大学出版社,1990:58.
[18] 钱振型.固体电子学中的等离子体技术[M].北京:电子工业出版社,1987:111,123.
[19] Amorim J.;Ricard A.;Baravian G. .PRODUCTION OF N, H, AND NH ACTIVE SPECIES IN N-2-H(2) DC FLOWING DISCHARGES[J].Plasma Chemistry and Plasma Processing,1995(4):721-731.
[20] Xi Chen .Plasma-particle Momentum Transfers under Conditions of Great Knudsen Numbers and Thin Plasma Sheath[J].Plasma Chemistry and Plasma Processing,1996,16(01):71s-82s.
[21] Andre P.;Lefort A.;Parizet MJ.;Abbaoui M. .NUMERICAL METHOD AND COMPOSITION IN MULTI-TEMPERATURE PLASMAS - APPLICATION TO AN AR-H-2 MIXTURE[J].Plasma Chemistry and Plasma Processing,1996(3):379-398.
[22] Ricard A.;Oseguera-Pena J.E. .Active species in microwave postdischarge for steel-surface nitriding[J].IEEE Transactions on Plasma Science,1990(6):940-944.
[23] Loureiro J;Ricard A .Electron and Vibrational Kinetics in an N2-H2 Glow Discharge with Application to Surface Processes[J].Journal of Physics D:Applied Physics,1993,26:163-176.
[24] James A D et al.NH(X3∑,v=1-3) Formation and Vibration Relaxation in Electron- irradiated Ar/N2/H2 Mixture[J].Journal of Chemical Physics,1991,94(06):4301-4310.
[25] Eckertová. L .薄膜物理学[M].北京:科学出版社,1986,12:3.
[26] 刘玉先;陈方生;徐军 .Distinguish Dislocation Loop From Stack Fault in Plasma Nitrided Layer by Rare-earth Catalytic[J].金属热处理学报,1998,19(04):60-64.
[27] 孙东升;李凤照;戴吉岩.Crystal Faults and Interfacial Structure of Ion NitridedLayer[J].金属学报,1993(05):A203.
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